Emotional education is an indispensable and important link in today’s educational philosophy. In college physical education, students’ emotions are often easily ignored, resulting in a feeling of weariness. What kind of method can effectively apply emotional education to physical education to improve students’ enthusiasm for learning has become one of the current research topics that has attracted much attention. Aiming at this problem, it has great research significance for the field of sports emotion education. With the deepening of emotional education research, the research on mobile Internet of Things (IoT) in college education continues to deepen, which is the key to solving the application problem of emotional education. The purpose of this paper is to study the application of college physical education and emotional education integrating mobile IoT model. Through the analysis and research of mobile IoT and emotional education, it can be applied to the construction of emotional education methods to solve the problem of improving students’ enthusiasm for learning. This paper analyzed mobile IoT, college physical education, and emotional education, which conducted experimental analysis of method functions and used related theoretical formulas to explain. The results have shown that the emotional education method is more effective than the traditional method in improving students’ enthusiasm for learning, and the difference between the two in the evaluation of teaching satisfaction is 31.89%. It can be seen that this kind of emotional education can meet the needs of improving students’ enthusiasm for learning, and the satisfaction and learning efficiency are greatly improved.