Universities are well placed to adopt and use the UN Sustainable Development Goals (SDGs) on their campuses to educate and showcase how the SDGs can be delivered in the built environment. Green infrastructure, such as green roofs, green walls, or green parks, are highly visual implementations with environmental and social benefits that contribute to several SDGs, such as 3 (good health and wellbeing), 10 (reduced inequalities), 11 (sustainable cities and communities), 13 (climate action) and 15 (life on land). These features may be referenced in sustainability teaching and learning, which may raise and heighten awareness of the social, economic, and environmental benefits of green infrastructure. In this study, we explored users’ perceptions of the extent to which a university campus green roof contributes to the SDGs and whether users focussed more on its social or environmental benefits. Statistical analyses, namely independent samples t-tests and analysis of variance, were conducted to determine what influenced users’ perceptions of the green roof. The analyses revealed that users’ perceptions did not differ largely by sociodemographic characteristics, though students perceived the social benefits as greater than university staff. Those with greater knowledge of green roofs perceived its environmental benefits as greater, but not the social benefits. The findings demonstrate the importance of green infrastructure on university campuses for encouraging engagement with the SDGs, whilst indicating that knowledge of such infrastructure increases appreciation of their environmental credentials.