In the present study, polyaniline (PANI) and ferrous oxide (Ī±āFe2O3) are amalgamated for ammonia sensing purpose. The hybrid nanocomposite is prepared by a single step in situ chemical oxidative polymerization of aniline in presence of hydrothermally prepared Ī±āFe2O3 nanoparticles. The structural and compositional analyses of the hybrid material are fully executed by FTIR, PXRD, and SEM techniques. A naive, exceedingly selective, quickly restorable, and ambient temperature functioning ammonia detecting device is established by using PANI/Ī±āFe2O3. The investigation results indicate that the PANI/Ī±āFe2O3 hybrid nanocomposite exhibits selective sensing ability towards ammonia vapors. The PANI/Ī±āFe2O3 displays excellent response for 5Ā ppm and maximum response for 100Ā ppm of ammonia. The response time of the PANI/Ī±āFe2O3 sensor is found to be quick with reasonably short recovery time. Due to excellent reusability, good environmental stability, and highly economical synthesis the PANI/Ī±āFe2O3 delivers a capable, simple, and efficient sensor system for ammonia detection at ambient temperature.