Sodium Periodate (NaIO4) in Organic Synthesis

Varala, Ravi; Dubasi, Narsimhaswamy; Seema, Vittal; Kotra, Vijay

doi:10.1055/a-2183-3678

SynOpen

2023

DOI: 10.1055/a-2183-3678

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Sodium Periodate (NaIO4) in Organic Synthesis

Ravi Varala,

Narsimhaswamy Dubasi,

Vittal Seema

et al.

Abstract: NaIO4 has been effectively investigated as a flexible oxidant for a range of fundamental chemical transformations, including the synthesis of bioactive natural compounds and intriguing oxidative transformations including C–H activation and oxidative functionalization of alkenes.

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2024

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Cited by 6 publications

References 53 publications

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Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Varala,

Seema,

Amanullah

et al. 2024

Journal of Heterocyclic Chem

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One of the most often utilized hydroperoxides in an array of oxidation strategies is tert‐butyl hydroperoxide (tBuOOH, TBHP). The key reasons for rising utility of TBHP are its low cost, environmental friendliness, high efficiency, and ability to replace hazardous or rare heavy metal oxidants. In this sexennial update, we concisely and critically discussed the applications of TBHP in heterocyclic ring formations starting from 2018 to date. Merits and demerits of its utility, scope of a synthetic organic transformation along with mechanistic logistics are the key features of this review.

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Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Varala,

Seema,

Amanullah

et al. 2024

Journal of Heterocyclic Chem

Self Cite

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tert‐Butyl Hydroperoxide (TBHP): Recent Progress in C−H Functionalization and Heteroatom‐Heteroatom Bond Formations

Varala,

Seema,

Hussein

et al. 2024

ChemistrySelect

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Abstracttert‐Butyl hydroperoxide (tBuOOH, TBHP) is a commonly used hydroperoxide in many oxidation processes. The primary factors contributing to the increasing usefulness of TBHP include its affordability, eco‐friendliness, exceptional efficacy, and capacity to substitute harmful or rare heavy metal oxidants. In this sexennial update, we thoroughly and critically examined the most noteworthy applications of TBHP in C−H functionalization and heteroatom‐heteroatom bond formation reactions from 2018 till the present. The review has been subdivided based on the nature of the bonds being formed. The review focuses on the advantages and disadvantages of using synthetic organic transformations, as well as the breadth of their use and the underlying mechanisms involved.

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Recent advances in metal-mediated oxidations with mCPBA

Varala,

Dhadda,

Seema

et al. 2024

Transit Met Chem

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Sodium Periodate (NaIO4) in Organic Synthesis

Abstract: NaIO4 has been effectively investigated as a flexible oxidant for a range of fundamental chemical transformations, including the synthesis of bioactive natural compounds and intriguing oxidative transformations including C–H activation and oxidative functionalization of alkenes.

Cited by 6 publications

References 53 publications

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

tert‐Butyl Hydroperoxide (TBHP): Recent Progress in C−H Functionalization and Heteroatom‐Heteroatom Bond Formations

Recent advances in metal-mediated oxidations with mCPBA

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