Optical lenses with high design freedom and different spatial orientations are highly attractive in laser processing, machine vision, optical communication, etc. Traditional optical lens processing is achieved by precision machining or injection moulding in combination with post grinding or polishing, which is expensive and highly complex and has little freedom to produce spatially distributed optic structures. The emerging additive manufacturing has exhibited significant advantages in printing multi-material, multi-scale, and multi-functional optical devices. Yet, the challenges of low printing speed and surface quality limits remain due to layer-based fabrication. To address this, we apply Tomographic Volumetric Printing (TVP) in this work, which cures the entire desired 3D geometry simultaneously by exploiting the threshold behavior of the photopolymerization process due to oxygen-induced polymerization inhibition. By coordinating the TVP and the meniscus equilibrium post-curing methods, ultra-fast fabrication of complex curved lenses with sub-nanometer roughness has been achieved. A 2.5 mm high, outer diameter 9 mm spherical lens with a sub-nanometric roughness of RMS = 0.3340 nm is printed at a speed of 3.1 × 104 mm3 h−1. As a further demonstration, a complex-shaped fly-eye lens is fabricated without any part assembly. The designed lens is mounted on a smartphone’s camera, and the precise alignment above the circuit board is captured. Upon further optimization, this new technology demonstrates the potential to rapidly prototype optical components or systems.