The demand of flexible energy storage devices for portable and wearable electronics has become increasingly urgent due to the rapid development of microelectronic products, wearable devices, and smart skin. [1][2][3][4][5][6] Some of the most effective and practical technologies for electrochemical energy conversion and storage are batteries, fuel cells, and supercapacitors. [7][8][9][10][11][12][13][14][15] Among them, supercapacitors (SCs) have attracted intensive attentions due to their high power density and long lifecycle. [9,13,[16][17][18] The energy storage is performed by ion adsorption or fast surface redox reaction at the interface between electrodes and electrolyte. Moreover, all-solid-state microsupercapacitors (MSCs) can greatly facilitate the development The graphene with 3D porous network structure is directly laser-induced on polyimide sheets at room temperature in ambient environment by an inexpensive and one-step method, then transferred to silicon rubber substrate to obtain highly stretchable, transparent, and flexible electrode of the all-solidstate planar microsupercapacitors. The electrochemical capacitance properties of the graphene electrodes are further enhanced by nitrogen doping and with conductive poly(3,4-ethylenedioxythiophene) coating. With excellent flexibility, stretchability, and capacitance properties, the planar microsupercapacitors present a great potential in fashionable and comfortable designs for wearable electronics.