The evolution of illegal refining was briefly discussed leading to an experimental research of its effects on cassava plant which is a major staple food in the region. Two deactivated illegal refinery sites were selected for the studies; cassava plant (tubers, stem and leaves) samples were taken from these sites with a control and then analyzed for the concentrations of Heavy Metals, BTEX, PAHs and THC. The results show that the mean concentration of heavy metals in cassava tuber were Pb (5.31±0.17 mg/kg), Cd (6.44±0.23mg/kg), Cr (5.25±0.02 mg/kg), As (9.27±0.04 mg/kg), Zn (5.30±0.17 mg/kg), Cu (4.17±0.06 mg/kg), Ni (13.52±0.01 mg/kg) and Co (40.66±0.00) (mg/kg) for site A; while site B has Pb (0.15±0.03 mg/kg), Cd (0.107±0.06 mg/kg), Cr (0.167±0.03 mg/kg), As (1.83±0.02 mg/kg), Zn (0.063±0.02 mg/kg), Cu (0.079±0.04 mg/kg), Ni (0.113±0.01 mg/kg) and Co (0.082±0.05 mg/kg). The mean concentration values of heavy metals in cassava tuber were higher than the control mean values. Plant Concentration Factor was also calculated from the studies. Result also showed higher mean concentration values of BTEX and PAHs for cassava plant (tuber, stem and leaves) when compared with control values and WHO permissible limits for plants. The overall result indicates the contamination and pollution of cassava plant from both studied sites due to illegal petroleum crude oil refining activities.