Solar driven CO2 hydrogenation to HCOOH on (TiO2)n (n = 1–6) atomic clusters

Tian, Jiaqi; Hou, Lei; Xia, Weizhi; Wang, Zi; Tu, Yusong; Pei, Wei; Zhou, Si; Zhao, Jijun

doi:10.1039/d3cp03473a

Phys. Chem. Chem. Phys.

2023

DOI: 10.1039/d3cp03473a

|View full text |Cite

Solar driven CO₂ hydrogenation to HCOOH on (TiO₂)_n (n = 1–6) atomic clusters

Jiaqi Tian,

Lei Hou,

Weizhi Xia

et al.

Abstract: Artificial photosynthesis is a crucial reaction that addresses energy and environmental challenges by converting CO2 into fuels and value-added chemicals. However, the efficient catalytic activity using earth-abundant materials can be...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

2025

Publication Types

Select...

Article5

Relationship

Self Cite1

Independent4

Authors

Journals

Cited by 5 publications

References 63 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Unraveling the evolution of oxygen vacancies in TiO2−x/Cu and its role in CO2 hydrogenation

Wang,

Zhang,

Cao

et al. 2024

Sci. China Chem.

View full text Add to dashboard Cite

Unraveling the evolution of oxygen vacancies in TiO2−x/Cu and its role in CO2 hydrogenation

Wang,

Zhang,

Cao

et al. 2024

Sci. China Chem.

View full text Add to dashboard Cite

Au atomic clusters on MoS2 nanosheets for hydrogen evolution reaction

Tian,

Hou,

Pei

et al. 2025

Surfaces and Interfaces

View full text Add to dashboard Cite

p-block germanenes as a promising electrocatalysts for the oxygen reduction reaction

Wang,

Xia,

Liu

et al. 2024

The Journal of Chemical Physics

View full text Add to dashboard Cite

The oxygen reduction reaction (ORR), a pivotal process in hydrogen fuel cells crucial for enhancing fuel cell performance through suitable catalysts, remains a challenging aspect of development. This study explores the catalytic potential of germanene on Al (111), taking advantage of the successful preparation of stable reconstructed germanene layers on Al (111) and the excellent catalytic performance exhibited by germanium-based nanomaterials. Through first-principles calculations, we demonstrate that the O2 molecule can be effectively activated on both freestanding and supported germanene nanosheets, featuring kinetic barriers of 0.40 and 0.04 eV, respectively. The presence of the Al substrate not only significantly enhances the stability of the reconstructed germanene but also preserves its exceptional ORR catalytic performance. These theoretical findings offer crucial insights into the substrate-mediated modulation of germanene stability and catalytic efficiency, paving the way for the design of stable and efficient ORR catalysts for future applications.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Solar driven CO₂ hydrogenation to HCOOH on (TiO₂)_n (n = 1–6) atomic clusters

Abstract: Artificial photosynthesis is a crucial reaction that addresses energy and environmental challenges by converting CO2 into fuels and value-added chemicals. However, the efficient catalytic activity using earth-abundant materials can be...

Cited by 5 publications

References 63 publications

Unraveling the evolution of oxygen vacancies in TiO2−x/Cu and its role in CO2 hydrogenation

Unraveling the evolution of oxygen vacancies in TiO2−x/Cu and its role in CO2 hydrogenation

Au atomic clusters on MoS2 nanosheets for hydrogen evolution reaction

p-block germanenes as a promising electrocatalysts for the oxygen reduction reaction

Contact Info

Product

Resources

About