China invests more in renewable energy than any other countries, such as in solar energy. The traditional literature maintains that these government-supported industries are more innovative than grassroots industries such as solar or thermal, which leads to debate. This study uses mixed methods, combining qualitative and quantitative approaches to compare the technology trajectories of leading solar water heater (SWH) and solar photovoltaic (PV) firms in China. It concentrates on the following three aspects: trajectories of key technologies, patent citation network, and type of collaboration. Our analyses show that technology trajectories differ significantly between leading SWH firms and PV firms in China. We find that the Chinese SWH firms are core to international knowledge networks, and are following a market-driven innovation mode. In contrast, Chinese PV firms are close to the center of the network and government-driven. Research suggests that grassroots innovation, by doing, using, and interaction (DUI), can create short-term market development models relying on China's traditional industry model, but cannot create a long-term international leading innovation model; only integrated science, technology, innovation modes (STI), and DUI innovation modes tend to result in international leadership in innovation.Solar PV and SWH are both low-carbon technologies that contribute to China's sustainable development. Yet, they have different technological, economic, and social characteristics and dynamics [7]. China is awakening to the need to fundamentally rethink the innovation pathways by which the two industries are developed and managed, for more effectively solving development bottlenecks, such as a lack of breakthrough innovations in the SWH industry and a lagging domestic market for the PV industry.This study uses mixed methods, combining qualitative and quantitative research approaches to compare the technology trajectories of leading solar water heater (SWH) and solar photovoltaic (PV) firms in China.This paper builds on previous research by Urban et al. [7] and uses patent analysis to examine the innovations of Chinese SWH and solar PV enterprises. Our main goal is to determine to what extent and how the PV and SWH patent knowledge bases differ in China.There is some literature on patent analysis for solar PV development in China [8], but less on SWH, and a knowledge gap exists regarding firm-level [9-11] technology pathways and innovation from a comparative-analysis perspective. According to Hu and Wang [12], 95% of SWH in China has the evacuated tube design. China Greentech Initiative (CGTI) estimates that Chinese firms hold 95% of the patents for core technologies of SWH worldwide [13]. However, academic research underpinning these figures is scarce. To observe the impact of technological innovation on enterprise expansion and market shares, and to provide empirical evidence for policy recommendations, this paper also explores the relationship between sales income and patent degree centrality through em...