The demand for renewable energy sources such as waste pyrolysis plastic oil (WPPO), ethanol biofuel with high oxygen content is increasing globally. This study used blending of conventional diesel oil, waste plastic pyrolysis oil, ethanol and 2-ethyl hexyl nitrate (EHN) as additive. The purpose was to improve combustion, the ignition quality, and performance and emission characteristics of WPPO as an alternative source of energy. As an additive EHN reduces emissions of CO, CO2, UHC, NOX, and PM. On the other hand, the inclusion of ethanol purposed to improve the viscosity, increase the oxygen content of the blends, and increase miscibility of WPPO. The study utilized the following ratios, 50/WPPO25/E25, 60/WPPO20/E20, 70/WPPO15/E15, 80/WPPO10/E10 and 90/WPPO5/E5 for conventional diesel (CD), WPPO and ethanol and EHN respectively. The ratio of the additive was determined by the percentage method based on the total quantity of the blended fuel and was calculated as 0.001 %. A complete Miscibility was observed to avoid phase separation during the study and experimentation, for the blended ratios of WPPO. The testing for performance and emission characteristics was conducted on a fixed bed, water-cooled, single cylinder diesel generator engine. The results were compared to ASTM standards and discussed using tables and figures. The results conclusively show very close densities of 792 kg/m 3 , 963 kg/m 3 , 825 kg/m 3 for WPPO, ethanol, EHN respectively, which are close to CD fuel at 845 kg/m 3 .