Water quality and anthropogenic loads in many, but not all, cases are related. Some water quality monitoring programs analyse samples for the presence of Escherichia coli. These bacteria can come from humans and animals. Human‐attributable effluent contains optical brighteners (OBs) from detergents. A convenient and affordable optical quantitative method giving a linear luminescence outcome over several orders of detergent concentrations in the water solution is demonstrated. The proposed method uses the common presence of OBs in detergents. Detergent concentration in water can be used as a surrogate indicator of resultant anthropogenic loads in water bodies. The proposed optical method with linear outcome over several ranges of detergent water concentrations is described.