(Solid+liquid) and (liquid+liquid) phase equilibria measurements and correlation of the binary systems {tri-iso-butyl(methyl)phosphonium tosylate+alcohol, or +hydrocarbon}

Liquid−Liquid Equilibria in Binary Mixtures Containing Substituted Benzenes with Ionic Liquid 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide

“…There are several solubility studies of RTIL mixtures with aromatic hydrocarbons and alkanes in the literature; [26][27][28][29][30][31][32][33][34] however, to the best of our knowledge, we are the first to report LLE for many of these substituted benzene isomers in [emim][Tf 2 N]. This report combines both our current work on the interactions of substituted benzenes and comparisons to our original measurements of benzene (C 6 …”

Mutual Solubility of Aromatic Hydrocarbons in Pyrrolidinium and Ammonium-Based Ionic Liquids and Its Modeling Using the Cubic-Plus-Association (CPA) Equation of State

“…A database of experimental binary liquid–liquid equilibria (LLE) data of different ILs with a broad range of hydrocarbons has been reported. By inspection of the literature available in the Scopus database, most of the references (25) are related to mixtures containing imidazolium-based ILs, while scarce publications about the phase behavior of binary mixtures with ILs based on other cations such as ammonium (3), phosphonium (3), pyridinium (7), pyrrolidinium (6), or quinolinium (7) have been found. − Because of the large number of {aromatic hydrocarbon (1) + ionic liquid (2)} potential mixtures, new solubility studies are needed since the solubility of aromatic compounds in the ILs affects their use as extraction media.…”

Determination of Activity Coefficients at Infinite Dilution of 35 Solutes in the Ionic Liquid, 1-Butyl-3-methylimidazolium Tosylate, Using Gas−Liquid Chromatography

“…1,2 Aliphatic hydrocarbons are weakly soluble in tosylate-based ionic liquids, whereas aromatic compounds are very soluble. [3][4][5][6][7][8][9] The results of solubility in the binary systems are a good indication that the ILs may show good separation of aromatics from aliphatics. It was shown by us using phase equilibria study of binary systems that aliphatic hydrocarbons have a low solubility and benzene and nalkylbenzenes a high solubility in the ILs: tetra-n-butylphosphonium tosylate, [B 4 P][TOS], 4 or tri-iso-butyl(methyl)phosphonium tosylate, [B 3 MP][TOS], 5 or 1-butyl-3-methylimidazolium tosylate, [BMIM][TOS], 6 or N-butyl-4-methylpyridinium tosylate, [BM 4 Py][TOS], 7 or N-butyl-3-methylpyridinium tosylate, [BM 3 Py][TOS].…”

“…[3][4][5][6][7][8][9] The results of solubility in the binary systems are a good indication that the ILs may show good separation of aromatics from aliphatics. It was shown by us using phase equilibria study of binary systems that aliphatic hydrocarbons have a low solubility and benzene and nalkylbenzenes a high solubility in the ILs: tetra-n-butylphosphonium tosylate, [B 4 P][TOS], 4 or tri-iso-butyl(methyl)phosphonium tosylate, [B 3 MP][TOS], 5 or 1-butyl-3-methylimidazolium tosylate, [BMIM][TOS], 6 or N-butyl-4-methylpyridinium tosylate, [BM 4 Py][TOS], 7 or N-butyl-3-methylpyridinium tosylate, [BM 3 Py][TOS]. 8 Recently, our group determinated the solidliquid equilibria (SLE) of thiophene with ionic liquids involving tosylate-based ILs: [BM 4 Py][TOS], or [BM 3 Py][TOS], or N-hexyl-3-methylpyridinium tosylate [HM 3 Py][TOS], or 1,4-dimethylpyridinium tosylate [M 1,4 Py][TOS], or 2,4,6-collidine tosylate [M 2,4,6 Py][TOS] at ambient pressure.…”