Solid-liquid phase equilibria of benzene + cyclohexane system under high pressures

A simple theoretical model for condensed-phase equilibria based on a hard-sphere equation-of-state and its applications

“…Further applications of this model to more complex phase behaviors than the present examples are encouraged. [20], and benzene [14,20].…”

“…a linear relationship of T and P. Proposed empirical SimonÕs equations (Eq. (26)) for benzene [14] and 1-methylnaphthalene [20] are plotted in Fig. 7 (dotted lines), compared with the hard-sphere model and experimental data.…”

“…Calculated results with the present model are compared with experimental data [13,14] in Fig. 6 at 0.1, 200 and 300 MPa.…”

Extended Veytsman statistics for the solid–fluid transition in the framework of lattice fluid

“…Activity coefficient models were generally used to model the solid-liquid equilibria of mixtures [6]. However, this approach is mainly limited to low pressure systems and requires different sets of parameters to describe even a simple eutectic system [7]. Meanwhile, EOS approach applicable to the solid-fluid equilibria is in an initial stage of development.…”

Raman Frequencies Calculated at Various Pressures in Phase I of Benzene

“…4 Also, solid−liquid phase equilibria of the benzene + cyclohexane system have been studied experimentally. 5 Measurements of the molar volume as functions of temperature and pressure have been reported with the molar volume discontinuities at melting in benzene. 6 Using the experimental data, 4,6 we have calculated the molar volume as a function of temperature 7 and pressure 8 close to the melting line in benzene in our earlier studies.…”