Solid—solid phase transitions determined by differential scanning calorimetry

Breed, L. W.; Murrill, E.

doi:10.1016/0040-6031(70)80027-2

Cited by 107 publications

(23 citation statements)

References 17 publications

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“…Compounds II and IV have * The support of the National Science Foundation is grate-* Gas heater, Model SGH 114680, Sylvania Special Profully acknowledged, ducts Division, Exeter, New Hampshire 03833, USA. (Murrill & Breed, 1970). The results of the two investigations are in good agreement.…”

Section: Referencessupporting

confidence: 78%

The formation of the plastic crystal phase in several pentaerythritol derivatives

Doshi¹,

Furman²,

Rudman³

1973

Acta Crystallogr Sect B

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Section: Referencessupporting

confidence: 78%

The formation of the plastic crystal phase in several pentaerythritol derivatives

Doshi¹,

Furman²,

Rudman³

1973

Acta Crystallogr Sect B

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“…Chains of molecules formed by weak hydrogen bonds have many degrees of freedom and numerous conformations. This supports the appearance of a solid state polymorphism [10][11][12]. For alcohols with linear molecules two crystalline phases were often observed [13].…”

Section: Introductionmentioning

confidence: 63%

DSC studies of neohexanol and its isomers

Juszyńska¹,

Massalska-Arodź²,

Zieliński³

et al. 2006

Phase Transitions

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DSC method has been used to establish a solid state polymorphism of four dimethyl butanols having CH 3 side groups:. Three isomers appear to be glass formers. Glass of liquid phase has been observed for 3,3-DM-1-B while glass of plastic phase for 2,2-DM-1-B and 3,3-DM-2-B. For 2,3-DM-2-B on cooling only crystallization has been found. Influence of location of the OH group in molecule on polymorphism is discussed. IR-spectra, measured in the liquid phase, have revealed hydrogen bonds in all isomers.

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“…The ability of these compounds to reversibly absorb or release a large amount of heat at the phase transition temperature during the solid-solid phase transition makes them attractive as solid state thermal energy storage materials. After the pioneering study of Murrill and Breed [4], numerous researchers have conducted thermodynamic and crystallographic studies on pure as well as binary mixtures to design new thermal energy storage materials (TES) for practical applications. A compilation of the thermodynamic and crystallographic properties of the compounds of interest to this study (AMPL, TRIS, and NPG) are shown in table 1.…”

Section: Thermal Energy Storage Materialsmentioning

confidence: 99%