Solid Standards in Fluorescence Spectrometry

McKinnon, Rona A.

doi:10.1016/b978-0-444-42880-6.50014-3

Cited by 3 publications

(2 citation statements)

References 3 publications

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“…This original design recognized the value of being able to carry out calibrations of fluorescent transfer standards under different specified geometries of irradiation and viewing. However, this approach was abandoned in the final version of this reference instrument which included only a well-characterized bidirectional (0:45) measurement geometry [19].…”

Section: Sphere-based Measurements-theorymentioning

confidence: 99%

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Characterization of a versatile reference instrument for traceable fluorescence measurements using different illumination and viewing geometries specified in practical colorimetry—part 2: sphere geometry (8:d)

et al. 2017

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Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n'arrivez pas à les repérer, communiquez avec nous à PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. Questions? Contact the NRC Publications Archive team atPublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. If you wish to email the authors directly, please see the first page of the publication for their contact information. NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. NRC Publications Record / Notice d'Archives des publications de CNRC:http://nparc.nrc-cnrc.gc.ca/eng/view/object/?id=d9682c21-38af-4e8e-8896-f53b13c69d2a http://nparc.nrc-cnrc.gc.ca/fra/voir/objet/?id=d9682c21-38af-4e8e-8896-f53b13c69d2a AbstractIn the second part of this two-part series on the development of a versatile reference instrument at the National Research Council of Canada (NRC), we have extended the characterization of t he NRC Reference Goniospectrofluorimeter to high-accuracy fluorescence measurements in a sphere geometry (8:d) that is specified in standard test methods for many practical applications in colorimetry. This builds upon the work reported in part-one of this series which described in detail the design, characterization and validation of this new instrument for realizing a total spectral radiance factor scale in a bidirectional (45a:0) geometry. To extend the measurement capabilities to a sphere geometry, it was configured with a large diameter integrating sphere accessory.Preliminary results using a substitution-mode operating procedure showed large sphere errors that were characterized and corrected for. To improve this traceability, the sphere was modified to operate in comparison-mode and this effectively eliminated many of the sphere-related errors t hat typically limit the accuracy of sphere-based fluorescence 2 measurements. The performance of the instrument configured for a sphere geometry

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Section: Sphere-based Measurements-theorymentioning

confidence: 99%

“…However, this approach was abandoned in the final version of this reference instrument which included only a well-characterized bidirectional (0:45) measurement geometry [19].…”

Section: Sphere-based Measurements -Theorymentioning

confidence: 99%

Characterization of a versatile reference instrument for traceable fluorescence measurements using different illumination and viewing geometries specified in practical colorimetry—part 2: sphere geometry (8:d)

et al. 2017

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Fluorescence Quantum Yields: Methods of Determination and Standards

Rurack

Springer Series on Fluorescence

123

119

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Determination of the photoluminescence quantum yield of dilute dye solutions (IUPAC Technical Report)

Resch‐Genger

Rurack

2013

Pure and Applied Chemistry

123

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Procedures for the determination of photoluminescence quantum yields with optical methods are addressed, and challenges associated with these measurements are discussed. Special emphasis is dedicated to relative measurements of fluorescent (i.e., short excitedstate lifetime), transparent, dilute dye solutions in conventional cuvettes in a 0°/90° measurement geometry. Recommendations on the selection of suitable quantum yield standards are presented, and requirements for the documentation of photoluminescence quantum yields are derived.

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Solid Standards in Fluorescence Spectrometry

Cited by 3 publications

References 3 publications

Characterization of a versatile reference instrument for traceable fluorescence measurements using different illumination and viewing geometries specified in practical colorimetry—part 2: sphere geometry (8:d)

Characterization of a versatile reference instrument for traceable fluorescence measurements using different illumination and viewing geometries specified in practical colorimetry—part 2: sphere geometry (8:d)

Fluorescence Quantum Yields: Methods of Determination and Standards

Determination of the photoluminescence quantum yield of dilute dye solutions (IUPAC Technical Report)

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