Solid state coordination chemistry of metal-1,2,4-triazolates and the related metal-4-pyridyltetrazolates

Ouellette, Wayne; Jones, Stephanie B.; Zubieta, Jon

doi:10.1039/c0ce00919a

Cited by 119 publications

(68 citation statements)

References 120 publications

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“…IR spectra (KBr pellets) were recorded on a Nicolet Impact 420 FT-IR spectrometer. 1 H NMR spectra were recorded on a Bruker DPX-400 spectrometer. Thermogravimetry and differential scanning calorimetry were measured on a NETZSCH STA 409 PC system in static air at a scanning rate of 10°C min -1 .…”

Section: Methodsmentioning

confidence: 99%

“…During the past several years, there has been considerable interest in the metalorganic frameworks (MOFs) constructed by metals and 1,2,4-triazoles (3-R 1 ,5-R 2 -tzH, R 1 and R 2 denotes 3,5-substituents) [1][2][3]. We and others have observed a prominent ''structure effect'' of 3,5-substituents even if they are only noncoordinative hydrocarbons; the structures of metal-triazole complexes are, more or less, dictated by the shape/size of the 3,5-substituents [4][5][6][7][8][9][10].…”

Section: Introductionmentioning

confidence: 99%

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Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

Zhang

Wang²,

et al. 2012

J Clust Sci

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The Ag(I) and Cu(I) complexes of 4-amino-3,5-dipentyl-4H-1,2,4-triazole (4-NH 2 -3,5-(C 5 H 11 ) 2 tz) and 3,5-dipentyl-1H-1,2,4-triazole (3,5-(C 5 H 11 ) 2 tzH) have been synthesized and characterized. X-Ray analysis shows that {Ag 4 [4-NH 2 -3,5-(C 5 H 11 ) 2 tz] 6 }(BF 4 ) 4 is a tetranuclear complex featuring an Ag 4 tz 6 cluster; {Ag[3,5-(C 5 H 11 ) 2 tz]} n exhibits a 3D structure of lvt-a topology; and {Cu 2 [3,5-(C 5 H 11 ) 2 tz]Br} n is a Cu 4 Br 4 -cluster based 3D complex with the dia topology.

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Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

Zhang

Wang²,

et al. 2012

J Clust Sci

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“…catalysis, luminescence, sorption, etc. [8][9][10][11][12][13][14][15][16]. In the context of Cu I /tz/X system (where tz is 1,2,4-triazolato anion, X is Cl -/Br -/I -), Zubieta and coworkers have prepared several 3D copper(I) or mixed-valent copper(I,II) triazolates having polymeric copper(I) halide subunits (e.g.…”

Section: Introductionmentioning

confidence: 99%

“…Calc. for C10 H 18 N 3 ClCu 2 (342.81): C, 35.04; H, 5.29; N, 12.26 %. Found: C, 35.04; H, 5.23; N, 12.15 %.…”

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confidence: 99%

Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X = Cl, Br)

Jin

Wang³

et al. 2014

J Clust Sci

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Reactions of 3,5-disubstituted-1,2,4-triazoles with CuX 2 (X = Cl, Br) under hydrothermal condition yield six copper(I) triazolates: [Cu 2 (3,5-n Bu 2 tz)Cl] n (1), [Cu 2 (3,5-i Bu 2 tz)Cl] n (2), {Cu 2 (3,5-(C 6 H 11 ) 2 tz)Cl} n (3), [Cu 2 (3,5-s Bu 2 tz)Br] n (4), {Cu 2 (3,5-(C 6 H 11 ) 2 tz)Br} n (5), {Cu 2 [3,5-(p-Tol) 2 tz]Br} n (6), where 3,5-n Bu 2 tz, 3,5-i Bu 2 tz, 3,5-s Bu 2 tz are 3,5-dibutyl-1,2,4-triazolate, 3,5-dii-butyl-1,2,4-triazolate, 3,5-dis-butyl-1,2,4-triazolate; 3,5-(C 6 H 11 ) 2 tz is 3,5-dicyclohexyl-1,2,4-triazolate; 3,5-(p-Tol) 2 tz is 3,5-di-p-tolyl-1,2,4-triazolate. X-ray analysis demonstrates that all of these complexes are isostructural and exhibit a 3D structure carrying cubic Cu 4 Cl 4 or Cu 4 Br 4 clusters. While 4 and 5 luminesce with maxima at 571 and 619 nm, others are silent under UV irradiation at room temperature.Keywords Copper(I) Á Triazole Á Structure Á Cu 4 Cl 4 cluster Á Cu 4 Br 4 cluster Electronic supplementary material The online version of this article (

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“…Recent years have witnessed a rapidly increasing interest in metal 1,2,4-triazolates due to their fascinating structures as well as some potential uses in materials science [1][2][3][4]. We have been concerned with the coordination chemistry of 1,2,4-triazole with Group 11 metals, with much attention being devoted to the possible structural role of the 3,5-substituents of triazole [5][6][7][8][9][10][11][12].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and crystal structures of silver(I) complexes of 3(5)-methyl-5(3)-phenyl-1H-1,2,4-triazole: two isomeric infinite chains coexisting in the same crystal

Zhang

Wei

Jin

et al. 2011

Transition Met Chem

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Reactions of 3(5)-methyl-5(3)-phenyl-1H-1,2,4-triazole (3-Me-5-Ph-tzH) with AgNO 3 in the absence/ presence of NH 3 yield a mononuclear [Ag(3-Me-5-Ph-tzH) 2 ] NO 3 Á3H 2 O (1) and a polymeric [Ag(3-Me-5-Ph-tz)] n (2), respectively. Two structurally different infinite chains, however, with the same formula of AgC 9 H 8 N 3 -one is doubledecked and the other single zigzag-coexist in 1:1 ratio in the crystal of 2. As far as we know, 2 is the first binary silver(I) complex based on an asymmetric triazole and represents a rare case of two supramolecular isomers coexisting in the same crystal.

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Solid state coordination chemistry of metal-1,2,4-triazolates and the related metal-4-pyridyltetrazolates

Cited by 119 publications

References 120 publications

Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X = Cl, Br)

Synthesis and crystal structures of silver(I) complexes of 3(5)-methyl-5(3)-phenyl-1H-1,2,4-triazole: two isomeric infinite chains coexisting in the same crystal

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