Metallic nanostructure plays a vital role in the nanoscale engineering of flexible optoelectronic devices as an active unit. Due to the limited flexibility properties of nanoparticles, the nanowires attracted much more researchers' attention these days for designing the flexible transparent electrode for different electronic devices. Silver nanowires possess a one-dimensional structure with a changeable aspect ratio. It also includes up-to-date properties for future optoelectronic devices, such as low cost, high conductivity, high transparency, and mechanical flexibility. Keeping in view the increasing demand for AgNWs, the commercial-scale synthesis of AgNWs is inevitable. But due to higher discrepancies among the published data, is the major holdup in its commercialization. Therefore, this review critically discusses those ignored factors, limiting the AgNWs commercialization and providing possible solutions.