Solid State Oxidation of Alcohols Using 1‐Butyl‐4‐aza‐1‐azoniabicyclo[2.2.2]octane Chlorochromate.

Abstract

Oxidation O 0212 Solid State Oxidation of Alcohols Using 1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane Chlorochromate. -A new and efficient methodology for the oxidation of aliphatic as well as aromatic alcohols to corresponding carbonyl compounds (II) (38 examples) under mild and solvent-free conditions is developed. -(HAJIPOUR*, A. R.; BAGHERI, H. R.; RUOHO, A. E.; Bull. Korean Chem.

Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation

“…In order to show the oxidative ability of the reagents (TMGCC and TMGFC), we compared some of our results with those of PCC [20], PFC [31,32], BAAOC [33], and DmpzHFC [34] carried out under solvent-free conditions (Table 5). a Yield was based on 2,4-dinitrophenylhydrazone derivative identified by melting point [29] (except for the 4-nitrobenzaldehyde and benzil whose melting points were taken directly).…”