Solid-state reaction among [CoCl4]2−, [CuCl4]2− and [CuCl4(H2O)]2− ions through transmetalation and liquid-assisted grinding

Li, Haitao; Guo, Zhenwei; Liu, Tie; Xin, Lianxin; Guo, Fang

doi:10.1039/d3ce01038d

CrystEngComm

2024

DOI: 10.1039/d3ce01038d

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Solid-state reaction among [CoCl₄]²⁻, [CuCl₄]²⁻ and [CuCl₄(H₂O)]²⁻ ions through transmetalation and liquid-assisted grinding

Haitao Li,

Zhenwei Guo,

Tie Liu

et al.

Abstract: Transformation of [CoCl4]2−, [CuCl4]2− and [CuCl4(H2O)]2− ions through transmetalation and LAG, monitored using AAS, PXRD and fluorescence spectroscopy.

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Metalo-Hydrogen-Bonded Organic Frameworks (MHOFs) Self-Assembled by Second-Sphere Coordination for Guest Exchange

Li,

Chao,

Liang

et al. 2024

Crystal Growth & Design

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Crystalline materials, such as metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs), have drawn much attention in a wide range of fields because of their controllable pore structures. Herein, using the second-sphere coordination approach, a series of metalo-hydrogen-bonded organic frameworks (MHOFs) have been synthesized through self-assembly of a bent-shaped organic dication H2 L (L = 4,4′-methylenedianiline) with X–, [MX4]2–, or [MX6]4– (X = Cl, Br; M = Cd, Pd, Sn), yielding networks with one-dimensional (1D) channels or semienclosed cages. The frameworks with a one-dimensional channel (1D) encapsulate water, forming a well-defined hydrogen bonding array, and are thermally stable while keeping the channels under melting point. The size of the channels is influenced by the anion, which results in the uptake of different liquid solvents by the channels after the removal of H2O.

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Metalo-Hydrogen-Bonded Organic Frameworks (MHOFs) Self-Assembled by Second-Sphere Coordination for Guest Exchange

Li,

Chao,

Liang

et al. 2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

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Solid-state reaction among [CoCl₄]²⁻, [CuCl₄]²⁻ and [CuCl₄(H₂O)]²⁻ ions through transmetalation and liquid-assisted grinding

Abstract: Transformation of [CoCl4]2−, [CuCl4]2− and [CuCl4(H2O)]2− ions through transmetalation and LAG, monitored using AAS, PXRD and fluorescence spectroscopy.

Cited by 1 publication

References 39 publications

Metalo-Hydrogen-Bonded Organic Frameworks (MHOFs) Self-Assembled by Second-Sphere Coordination for Guest Exchange

Metalo-Hydrogen-Bonded Organic Frameworks (MHOFs) Self-Assembled by Second-Sphere Coordination for Guest Exchange

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