Solid-state sodium batteries with P2-type Mn-based layered oxides by utilizing anionic redox
Steven Kmiec,
Panawan Vanaphuti,
Arumugam Manthiram
Abstract:Recently, P2-type manganese-based sodium layered cathodes have gained considerable attention as a viable option for grid-scale energy storage due to their high natural abundance, low cost, and high specific capacity...
“…9–11 The quest for reliable cathode materials is of paramount importance in meeting the escalating demand for renewable energy systems. 12,13 Among various cathode compounds, layered oxides (Na x TMO 2 , 0 < x ≦ 1; TM stands for transition metals, especially nickel and manganese) exhibit desirable characteristics such as excellent conductivity and high capacity. 14–17 Moreover, the manufacturing techniques for oxide cathodes align well with those employed for commercial LIB cathodes, particularly LiNi 1/3 Mn 1/3 Co 1/3 O 2 .…”
Sr2+, the “pillar” in the P2 structure, suppresses the phase transition, inhibits the Jahn–Teller distortion, and improves the performance of layered oxide cathodes in SIBs.
“…9–11 The quest for reliable cathode materials is of paramount importance in meeting the escalating demand for renewable energy systems. 12,13 Among various cathode compounds, layered oxides (Na x TMO 2 , 0 < x ≦ 1; TM stands for transition metals, especially nickel and manganese) exhibit desirable characteristics such as excellent conductivity and high capacity. 14–17 Moreover, the manufacturing techniques for oxide cathodes align well with those employed for commercial LIB cathodes, particularly LiNi 1/3 Mn 1/3 Co 1/3 O 2 .…”
Sr2+, the “pillar” in the P2 structure, suppresses the phase transition, inhibits the Jahn–Teller distortion, and improves the performance of layered oxide cathodes in SIBs.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.