Solid-state storage batteries

Liang, C. C.; Joshi, A. V.; Hamilton, N.

doi:10.1007/bf00615840

Cited by 83 publications

(28 citation statements)

References 8 publications

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“…The solid electrolyte is a dispersion of LiI and LiOH with alumina. Lithium ionic conductivities as high as 10 À4 S cm À1 have been reported in such a dispersion at temperature of 25 C [52]. The discharge properties are characterized by an opencircuit voltage of 1.9 V and an energy density of 75-150 Wh kg À1 .…”

Section: Li/lii-al 2 O 3 /Pbi 2 Cellsmentioning

confidence: 99%

Lithium Batteries

et al. 2016

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Section: Li/lii-al 2 O 3 /Pbi 2 Cellsmentioning

confidence: 99%

Lithium Batteries

et al. 2016

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“…Based on the Li/TiS~ couple, practical battery investigations have shown (6)(7)(8)) that a specific energy in the range of 100-150 Wh/kg is a realistic goal for moderate temperature batteries. This can be compared with the 50-60 Wh/kg goal for advanced lead acid systems.…”

mentioning

confidence: 99%

“…Alkali metal anodes dictate the use of nonaqueous electrolytes, either organic solvents with a M salt (10), or solid ionic conductors (7). [2] is basically a solid-state reaction, whose rate is controlled by diffusion of M + into the insertion compound particle.…”

mentioning

confidence: 99%

The Composite Insertion Electrode: Theoretical Part. Equilibrium in the Insertion Compound and Linear Potential Dependence

Atlung

Zachau‐Christiansen

West

et al. 1984

J. Electrochem. Soc.

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The specific energy obtainable by discharge of porous insertion electrodes is limited by electrolyte depletion in the pores. This can be overcome using a solid ion conductor as electrolyte. The term “composite” is used to distinguish these electrodes from porous electrodes with liquid electrolyte. The theoretical basis for such electrodes is discussed and, using a simplified model, equations are derived to describe the distribution of potential and current during discharge/charge operation. Under the assumption that the insertion compound particles are small enough to ensure equilibrium, and that the local electrode potential depends linearly on the degree of insertion, these equations are solved to obtain analytical expressions for the discharge curve. It is shown that the parameters which determine the discharge behavior for a given discharge current are simply related to the effective ionic and electronic conductivities, the thickness of the electrode, the volume fractions, and the slope of the potential curve.

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“…were dispersed into AgI, AgCl, LiI, CuI, AgBr, LiCl etc. (termed as a first-phase host matrix) [1][2][3][4][5][6]. Various theoretical models such as space-charge models [7], discrete-shell model [8], Pack's model [9], resister network model [10], percolation model [11] and concentration gradient model [12] etc.…”

Section: Introductionmentioning

confidence: 99%

“…Generally fast Ag + ion conducting two-phase composite electrolyte system was prepared using AgI as a host salt. A large number of such types of composite electrolyte systems have been reported [2][3][4][5]. In the present investigation we report here the ionic behavior of a newly synthesized Ag + ion conducting two-phase composite electrolyte system: 0.85 [0.75AgI:0.25AgCl]:0.15CeO 2 using a quenched/ annealed [0.75AgI:0.25AgCl] mixed system/solid solution, in place of the convential host AgI, which was recently established by Agrawal and co-workers [19].…”

Section: Introductionmentioning

confidence: 99%