This chapter is intended to present the basic concept of roll bonding (RB) and accumulative roll bonding (ARB) of light-weight ductile metals. For this purpose, a discussion on previous research works on RB and ARB has been incorporated in this chapter. The general mechanisms of joining after rolling and several applications of RB and ARB have also been discussed. In the present study, an investigation on influence of various parameters on joint strength was conducted. Preheat temperature and percentages of thickness reduction are found to influence joint strength in a significant manner. The influence of annealing temperature and annealing time on mechanical properties of roll-bonded products in terms of controlling parameters has also been discussed here. The significant influence of preheat temperature and corresponding thickness reduction on the bond strength has been thoroughly discussed with a mechanism of peel testing. An attempt has been made to establish the mechanism behind failure along the joining line during peel testing of bond strength of solid-state welding through rolling.