The composite structure of aluminium alloy and stainless steel provides a wide range of comprehensive advantages, encompassing properties such as lightweight, high strength, and corrosion resistance. These advantages make composite structure particularly suitable for various applications in industries such as transportation and chemicals. One innovative solid-phase welding technology that is well suited for joining dissimilar materials is vaporizing foil actuator welding. This technology allows for the welding of composite structures made of aluminium and stainless steel, despite the significant differences in physical and chemical properties. To enhance the vaporizing welding process, this paper proposes the introduction of an interlayer between the dissimilar materials. The interlayer consists of a third material that is added to bridge the gap between materials with differing hardness and plasticity. The main objective of introducing the interlayer is to minimise performance disparities and reduce the formation of intermetallic compounds at the interface. By examining the vaporizing foil actuator welding process of aluminium alloy and stainless steel with the interlayer, it aims to analyse the characteristics of the interface morphology. Additionally, this study investigates the energy conversion mechanism of the aluminium foil gasification process and explore the influence of the interlayer on the microstructure and mechanical properties of the interface between aluminium alloy and stainless-steel joints.