Solidification mechanism of modified silumins

Parkhutik, P. A.; Kalashnik, L. D.; Solov'ev, S.P.

doi:10.1007/bf00679209

Cited by 2 publications

(1 citation statement)

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…This is due to the effects of Sr on the activation energy for nucleation of eutectic Si in two aspects. On one hand, alkali and alkaline earth metals are generally both surface-active elements, which can reduce the interface energy between solid and liquid [33,34,35]. On the other hand, Srirangam et al [36] reported that Sr atoms bond prior to Si atoms to poison and inactivate the nucleation and growth sites of Si—thereby delaying the nucleation and growth of Si.…”

Section: Discussionmentioning

confidence: 99%

Simultaneous Refinement of Primary Si and Modification of Eutectic Si in A390 Alloy Assisting by Sr-Modifier and Serpentine Pouring Channel Process

et al. 2019

View full text Add to dashboard Cite

In this study, A390 alloy was prepared using the combined process of a water-cooled copper serpentine pouring channel (SPC) and strontium (Sr) modifier, in order to simultaneously refine primary silicon (Si) and modify eutectic silicon (Si). The nucleation and growth mechanisms of the Si phase were discussed by morphology analysis and non-isothermal analytical kinetics. The results indicate that the size of primary Si is refined to 25.2–28.5 µm and the morphology of eutectic Si is modified from acicular into fibrous. The serpentine pouring channel process stimulates primary Si nucleation due to chilling effect and has no influence on eutectic Si nucleation. Impacts of Sr-modifier on primary and eutectic Si are similar, including three aspects: (1) poisoning of the nucleation site; (2) decreasing the interface energy between Si phase and liquid; (3) raising the activation energy for diffusion across solid-liquid interface. The content of Sr determines which one of the three aspects mentioned above is the dominant factor to promote or restrain the nucleation and growth of the primary and eutectic Si in hypereutectic Al-Si alloy.

show abstract