Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-pro t purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. We study the dynamics of large polarons in diatomic molecular chains, at zero temperature, under the influence of an external, periodic in time, electric field with zero mean value. We show that in asymmetric chains, i.e., chains with two different atoms per unit cell, a harmonic unbiased field causes a drift of such polarons. Such a drift current, known as ratchet phenomenon, depends strongly on the parameters of the chain; in particular, on the extent of the anisotropy of the chain and on the size of the polaron. Moreover, the drift takes place only if the intensity and the period of the field exceed some critical values which also depend on the parameters of the chain. We show, that this directed current of polarons is a complicated phenomenon. It takes place in dissipative systems with a broken spatial symmetry, and is generated by the interplay between the PeierlsNabarro barrier and the impact of the external field on the charged polarons. The dependence of the amplitude of the polaron oscillations, the size of the drift per period of the external field and the average velocity are determined as a function of the intensity of the field and of its frequency.