Solubility of Anthracene in Ternary Propanol + Butanol + Heptane Solvent Mixtures

Deng, Taihe; Childress, Sabrina D.; Fina, Karina M. De; Acree, William E.

doi:10.1080/00986449908912771

Cited by 38 publications

(37 citation statements)

References 4 publications

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“…The predictive expression for the ternary solvent mixture is a mole fraction average of the logarithmic solute solubilities in the three pure solvents [(x A sat ) B , (x A sat ) C , and (x A sat ) D ] plus a Redlich-Kister summation term for each solvent pair. The documented success [11][12][13][14][15][16] of eq 4 in predicting anthracene solubilities in more than 60 different ternary solvent systems illustrates the need for measured solute solubilities in binary solvent mixtures.…”

Section: Resultsmentioning

confidence: 99%

Solubility of Anthracene in Binary Alcohol + Methyl Acetate Solvent Mixtures at 298.2 K

Acree

2001

J. Chem. Eng. Data

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Experimental solubilities are reported for anthracene dissolved in eight binary alcohol + methyl acetate solvent mixtures at 25°C. The alcohol cosolvents studied were 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 1-pentanol, 2-pentanol, and 3-methyl-1-butanol. Results of these measurements are used to test two mathematical representations based upon the combined nearly ideal binary solvent (NIBS)/Redlich-Kister and modified Wilson equations. For the eight systems studied, the combined NIBS/ Redlich-Kister equation was found to provide the better mathematical representation of the experimental data, with overall average absolute deviations between measured and calculated values being approximately (0.5%. Considerably larger deviations were noted in the case of the modified Wilson equation.

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Section: Resultsmentioning

confidence: 99%

Solubility of Anthracene in Binary Alcohol + Methyl Acetate Solvent Mixtures at 298.2 K

Acree

2001

J. Chem. Eng. Data

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“…Equation 1 has been shown to provide very accurate mathematical representations of anthracene, pyrene, and carbazole solubilities in a large number of both complexing and noncomplexing solvent mixtures. [1][2][3] For a ternary solvent system, the mathematical representation takes the form Recent studies have shown that eq 2 provides reasonably accurate predictions for anthracene solubilities in ternary two alkane + alcohol 10,11 and alkane + two alcohol [12][13][14] * To whom correspondence should be addressed. E-mail: acree@unt.edu.…”

Section: Resultsmentioning

confidence: 99%

Solubility of Pyrene in Ternary Propanol + Butanol + Heptane Solvent Mixtures at 299.15 K

et al. 2001

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Experimental solubilities are reported for pyrene dissolved in ternary 1-propanol + 1-butanol + heptane, 2-propanol + 1-butanol + heptane, 1-propanol + 2-butanol + heptane, and 2-propanol + 2-butanol + heptane solvent mixtures at 26°C and atmospheric pressure. Nineteen compositions were studied for each of the four solvent systems. Results of these measurements are used to test the predictive ability of the ternary solvent form of the combined NIMS/Redlich-Kister equation. Computations showed that the model predicted the observed solubility behavior to within an overall average absolute deviation of about 1.6%, which is comparable to the experimental uncertainty of (1.5%.

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“…Acree and co-workers [7][8][9]11,16,26,28 measured the solubility of anthracene in ternary heptane + alcohol + alcohol, cyclohexane + alcohol + alcohol, and 2,2,4-trimethylpentane + alcohol + alcohol solvent mixtures at 298.15 K. Alcohol cosolvents included 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, and 1-pentanol. There has only been a single experimental determination for the solubility of anthracene in each of the ternary solvent systems studied.…”

Section: Critical Evaluation Of Experimental Solubility Datamentioning

confidence: 99%

“…Original Measurements: (1) Pyrene; C 16 : initial mole fraction of component 3 in the ternary solvent mixture, x 4 (s) : initial mole fraction of component 4 in the ternary solvent mixture; x 1 : mole fraction solubility of the solute; x 3 : mole fraction of component 3 in the quaternary solution; x 4 : mole fraction of component 4 in the quaternary solution.…”

Section: Componentsmentioning

confidence: 99%

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures

Acree

2013

Journal of Physical and Chemical Reference Data

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This work updates Vols. 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in ternary organic solvent mixtures. Published solubility data for anthracene, phenanthrene, and pyrene that appeared in the primary literature between 1995 to the end of 2011 are compiled and critically evaluated. Experimental solubility data for 119 different solute-ternary solvent systems are included in the volume. Solubility data published prior to 1995 were contained in three earlier volumes (Vols. 54, 58, and 59) and are not repeated here.

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Solubility of Anthracene in Ternary Propanol + Butanol + Heptane Solvent Mixtures

Cited by 38 publications

References 4 publications

Solubility of Anthracene in Binary Alcohol + Methyl Acetate Solvent Mixtures at 298.2 K

Solubility of Anthracene in Binary Alcohol + Methyl Acetate Solvent Mixtures at 298.2 K

Solubility of Pyrene in Ternary Propanol + Butanol + Heptane Solvent Mixtures at 299.15 K

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures

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