Solubility of N,N′-Di(1-naphthyl)-N,N′-diphenyl Benzidine (NPB) in Various Organic Solvents: Measurement and Correlation with the Hansen Solubility Parameter

Abstract

the coefficients (a = 0.0102 MPa -1 and b = 2.16) and the HSP of NPB ( D  = 22.6 MPa 1/2 , P  = 6.8 MPa 1/2 , and H  = 5.8 MPa 1/2 for the dispersion, polarity, and hydrogen bonding interactions, respectively). The correlation enabled us to describe the solvent dependence of the solubility of NPB within the root-mean-square deviation of 0.47 in 2 log x from the experimental data. ) Reichardt, C.; Welton, T., Solvents and Solvent Effects in Organic Chemistry. 4th. ed.; Wiley-VCH: Weinheim, 2010.

Solubilities of Organic Semiconductors and Nonsteroidal Anti-inflammatory Drugs in Pure and Mixed Organic Solvents: Measurement and Modeling with Hansen Solubility Parameter

“…The calculated solubilities are compared with the experimental or literature ones to test the prediction. For NPB, we have the solubility data in 16 solvents other than the representative ones measured in our previous study . For anthracene, a number of literature solubility data are available in IUPAC-NIST Data Series 58 and 98. , The literature data agree well with our experimental results in the seven representative solvents, as shown in Figure and Table S5. − Thus, the literature data in other solvents (60 solubility data in 51 solvents) , were used for the validation of the calculated solubilities.…”

“…The HSP analysis seems to be rather primitive but has an advantage in the solvent screening, especially in finding the optimum solvent mixture, because the maximum solubility is directly related to the minimum Hansen distance. In our previous work, we measured the solubility of an organic semiconductor, N , N ′-di-1-naphthyl- N , N ′-diphenylbenzidine (NPB), in 23 organic solvents and quantitatively correlated it with the Hansen distance . Here we extend the solubility measurement and modeling to other organic semiconductors including an NPB analogue and three polycyclic aromatic hydrocarbons (PAHs) as well as to four nonsteroidal anti-inflammatory drugs (NSAIDs).…”

Improving the Solubility of Artificial Ligands of Streptavidin to Enable More Practical Reversible Switching of Protein Localization in Cells

“…Next, we measured the physical properties of these derivatives to see whether they might be suitable for cellular experiments. In particular, water solubility was evaluated over the concentration range where linearity of absorbance was maintained (Figure S3) . Log P was measured by reversed‐phase thin layer chromatography .…”

Solubility and Solubility Modeling of 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene toward Nanodispersions in Organic Solvents

“…Organic light-emitting diodes (OLEDs) have increasingly attracted interest in the display and illumination fields , and are developing toward large-scale production and flexibility. − Solution-processed technology has been considered as a next-generation manufacturing method for OLED production. − The dispersion or solution of organic functional materials of OLEDs in solvents is critical for the preparation of inks toward solution-processed devices. , For some kinds of currently used materials that are not highly soluble in common solvents that are suitable for printing processing, their applications in solution-processed OLED devices would be limited. Theoretically, according to the Ostwald–Freundlich equation, reducing the particle size is beneficial to increase the solubility of the solute in the solvent .…”

“…7−10 The dispersion or solution of organic functional materials of OLEDs in solvents is critical for the preparation of inks toward solution-processed devices. 11,12 For some kinds of currently used materials that are not highly soluble in common solvents that are suitable for printing processing, their applications in solution-processed OLED devices would be limited. Theoretically, according to the Ostwald−Freundlich equation, reducing the particle size is beneficial to increase the solubility of the solute in the solvent.…”