In this work, isothermal gas−liquid equilibrium (GLE) data were measured for the mixture SO 2 + N 2 in the system of triethylene glycol (TEG) + dimethyl sulfoxide (DMSO) at T = (298.15, 303.15, and 308.15) K and p = 123.15 kPa. Henry's law constants (HLCs) were obtained by fitting the linear slope of the GLE data. The results indicated that the solubility of dilute SO 2 in the system of TEG + DMSO increased with the increasing DMSO concentrations, and HLCs decreased with the increasing temperatures. The regeneration experimental results showed that the absorption of SO 2 in the binary system was reversible, and the solvent could be reused without significant loss of absorption capacity. Additionally, FTIR, UV−vis, and 1 H NMR spectral results indicated that intermolecular hydrogen bonding association among TEG, DMSO, and SO 2 molecules was formed.