Solubility of some lithium and aluminum halides in a mixed diethyl ether-toluene solvent

Mikheeva, V.I.; Arkhipov, S.M.; Pruntsev, A. E.

doi:10.1007/bf00946437

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“…Lithium iodide is moderately soluble in ethers 29 and can react with diethyl ether. 30 Therefore, we can speculate that LiI dissolution and eventually some reactions happened during the wet step of pulverization. The interface and eventually the bulk of the treated LiI-LPS could have been affected.…”

Section: Resultsmentioning

confidence: 99%

Study of Graphite Cycling in Sulfide Solid Electrolytes

Höltschi

Jud

Borca

et al. 2020

J. Electrochem. Soc.

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We report the excellent cycling stability of graphite in combination with two types of sulfide solid electrolytes, 0.75Li2S-0.25P2S5 (LPS) and 0.3LiI-0.7(0.75Li2S-0.25P2S5), and discuss the stability of the graphite-solid electrolyte interface by analyzing the normalized cumulative irreversible charge and the total amount of lithium consumed at the lithiated state. The rate limitations and the influence of the morphology and the size of graphite particles on the utilization of the electrode are studied as well. At higher current densities, the utilization of the graphite is decreasing as a consequence of the poor effective ionic conductivity of the composite electrode, which is also evidenced by the increasing polarization and ohmic resistance across the electrode.

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Section: Resultsmentioning

confidence: 99%