Solution calorimetry to assess effects of water-cement ratio and low temperature on hydration heat of cement

At present, the research on the high temperature degradation of concrete usually focuses on only the degradation of concrete itself without considering the effect of the plastering layer. It is necessary to take into account the influence of the plastering layer on the high temperature degradation of concrete. With an increase in the water/cement ratio, the explosion of concrete disappeared. Although increasing the water/cement ratio can alleviate the cracking of concrete due to lower pressure, it leads to a decrease in the mechanical properties of concrete after heating. It is proved that besides the water/cement ratio, the apparent phenomena and mechanical properties of concrete at high temperature can be affected by the plastering layer. The plastering layer can relieve the high temperature cracking of concrete, and even inhibit the high temperature explosion of concrete with 0.30 water/cement ratio. By means of an XRD test, scanning electron microscope test and thermogravimetric analysis, it is found that the plastering layer can promote the rehydration of unhydrated cement particles of 0.30 water/cement ratio concrete at high temperature and then promote the mechanical properties of concrete at 400 °C. However, the plastering layer accelerated the thermal decomposition of C-S-H gel of concrete with a water/cement ratio of 0.40 at high temperature, and finally accelerate the decline of mechanical property of concrete. To conclude, the low water/cement ratio and plastering layer can delay the deterioration of concrete at high temperature.

Section: Discussion Of Resultsmentioning

confidence: 99%

Section: Compressive Strengthmentioning

confidence: 99%

High Temperature Degradation Mechanism of Concrete with Plastering Layer

Liu

Chen

2022

“…As shown in Figure 10 , the cumulative heat of hydration increases with the addition of SAP. The cumulative heat of hydration of both samples OPC–0.25SAP and OPC–0.5SAP was higher than that of the control after 24 h. The water entrained in SAP increased the w/c, and the higher w/c increased the degree of hydration of the sample, resulting in a higher cumulative hydration heat [ 43 ]. In contrast, the cumulative hydration heat of the BPC–0SAP samples was much lower compared to the control group.…”

Section: Resultsmentioning

confidence: 99%

Effect of Cement Types and Superabsorbent Polymers on the Properties of Sustainable Ultra-High-Performance Paste

Xuan

Wang

et al. 2021

This study focuses on the effects of superabsorbent polymers (SAP) and belite-rich Portland cement (BPC) on the compressive strength, autogenous shrinkage (AS), and micro- and macroscopic performance of sustainable, ultra-high-performance paste (SUHPP). Several experimental studies were conducted, including compressive strength, AS, isothermal calorimetry, X-ray diffraction (XRD), thermogravimetric analysis (TGA), attenuated total reflectance (ATR)–Fourier-transform infrared spectroscopy (FTIR), ultra-sonic pulse velocity (UPV), and electrical resistivity. The following conclusions can be made based on the experimental results: (1) a small amount of SAP has a strength promotion effect during the first 3 days, while BPC can significantly improve the strength over the following 28 days. (2) SAP slows down the internal relative humidity reduction and effectively reduces the development of AS. BPC specimens show a lower AS than other specimens. The AS shows a linear relationship with the internal relative humidity. (3) Specimens with SAP possess higher cumulative hydration heat than control specimens. The slow hydration rate in the BPC effectively reduces the exothermic heat. (4) With the increase in SAP, the calcium hydroxide (CH) and combined water content increases, and SAP thus improves the effect on cement hydration. The contents of CH and combined water in BPC specimens are lower than those in the ordinary Portland cement (OPC) specimen. (5) All samples display rapid hydration of the cement in the first 3 days, with a high rate of UPV development. Strength is an exponential function of UPVs. (6) The electrical resistivity is reduced due to the increase in porosity caused by the release of water from SAP. From 3 to 28 days, BPC specimens show a greater increment in electrical resistivity than other specimens.

“…The porosity and pore structure of concrete are closely related to the water–cement ratio ( W / C ) and the degree of hydration ( α ) [ 30 ]. It has been reported that the degree of hydration can reach as high as 0.89 when the W / C is 0.3 [ 31 ].…”

Section: Models and Numerical Simulationsmentioning

confidence: 99%

Exploring Exact Effects of Various Factors on Chloride Diffusion in Cracked Concrete: ABAQUS-Based Mesoscale Simulations

Zhao

Guan

2023

Chloride ion attack is a major cause of concrete durability problems, and existing studies have rarely addressed the effects of damage zones. In this paper, an improved mesoscale model including five phases was constructed using the finite element software ABAQUS to study the diffusivity of chloride ions in cracked concrete. It was found that the damage zone is negligible when the crack width is less than 50 μm, while the width and depth of the damage zone are about 15 times the crack width and 15% of the crack depth when the crack is greater than 50 μm. The results show that the diffusion of chloride is greatly influenced by the crack width, while it is little-influenced by the crack shape. Low water–cement ratio and adequate hydration of the concrete are also key factors affecting chloride diffusion. In contrast, regular rounded aggregates have a positive effect on reducing chloride diffusion compared to irregularly shaped aggregates, and this effect becomes weaker with increasing service time. In addition, the protective layer can effectively prevent the diffusion of chloride in concrete. Therefore, when designing marine concrete, efforts should be made to ensure that the concrete has a low water–cement ratio, adequate hydration, less cracking and a protective layer.