Solution enthalpies of NaCl and NaI in water with 1,2-ethanediol, 1,2-propanediol, 1,2-butanediol and 1,2-pentanediol at 298.15 K

Thermochemical properties of electrolyte solutions in {2-(2-methoxyethoxy)ethanol+water} and (2-isopropoxyethanol+water) mixtures at 298.15 K

“…As it is seen, the values of h xy for both electrolytes taking into a consideration with each 2-alkoxyethanol are similar, within error limits. Earlier, the analogous behaviour was observed for aliphatic alcohols (from methanol to butanol [28], except t-butanol) and ethylene glycol [29].…”

Enthalpic interaction coefficients of NaI–alkanediol pairs in methanol and in water

“…The dissolution enthalpies of sodium iodide in the mixture investigated, D sol H, were measured with the use of an ''isoperibol'' calorimeter [7]. The relative error of measurement was D sol H ± 1.42%.…”

“…Systems containing an electrolyte and non-electrolyte in aqueous and N,N-dimethylformamide (DMF) solutions have been of interest to our laboratory for a long time [1][2][3][4][5][6][7][8]. In order to analyze intermolecular interactions in the systems under investigation the so-called enthalpic interaction coefficients model, derived from McMillan-Mayer's theory, was used [9].…”

“…The observations of the alkanediol-methanol mixtures investigated were interesting enough to impel us to compare the interactions between an electrolyte such as NaI and alkanediol in methanol with analogous interactions in water on the basis of enthalpic pair interaction coefficients, h xy . In order to get more data for such comparison the data concerning aqueous solutions [7,16] were completed with those for the systems: NaI-1,3-propanediolwater and NaI-1,2-pentanediol-water.…”

Experimental study of the excess molar volume of ternary mixtures containing {water+(1,2-propanediol, or 1,3-propanediol, or 1,2-butanediol, or 1,3-butanediol, or 1,4-butanediol, or 2,3-butanediol)+electrolytes} at a temperature of 298.15K and atmospheric pressure

“…Experimental study of the enthalpic behavior in aqueous mixtures containing alkanediols due to presence of electrolytes were performed by Checoni and Francesconi [5], Taniewska-Osinska and Pietrzac [11,12] and Pietrzac et al [13]. However, studies involving the influence of an electrolyte on V E m of aqueous mixtures, specially containing alkanediols, are inexistent.…”