2022
DOI: 10.1002/ente.202200819
|View full text |Cite
|
Sign up to set email alerts
|

Solvation and Stabilization of Superior Alanate Nanostructures

Abstract: NaAlH4 and LiAlH4 are promising materials for hydrogen storage due to their high hydrogen density (7.4 and 10.5 mass%, respectively). However, their practical application is hampered from the slow hydrogen kinetics and poor reversibility. To improve the hydrogen properties of alanates, the alternative core–shell strategy has been proposed. In this respect, a simple solvent evaporation method is presented to synthesize the alanate core. In this approach, NaAlH4 and LiAlH4 are stabilized by solvation and electro… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1

Citation Types

0
2
0

Year Published

2024
2024
2025
2025

Publication Types

Select...
5

Relationship

0
5

Authors

Journals

citations
Cited by 5 publications
(2 citation statements)
references
References 77 publications
0
2
0
Order By: Relevance
“…In addition, a prominent absorption at 1605 cm −1 belonging to NaI was observed in the PVA–Na electrolyte, with the signal intensity of the covered portion being greater than the uncovered portion. [ 35 ] This observation indicates a higher NaI concentration in the covered part of the PVA–Na electrolyte. Further corroboration of this finding was provided by the EDS mapping of the SEM images.…”
Section: Resultsmentioning
confidence: 96%
“…In addition, a prominent absorption at 1605 cm −1 belonging to NaI was observed in the PVA–Na electrolyte, with the signal intensity of the covered portion being greater than the uncovered portion. [ 35 ] This observation indicates a higher NaI concentration in the covered part of the PVA–Na electrolyte. Further corroboration of this finding was provided by the EDS mapping of the SEM images.…”
Section: Resultsmentioning
confidence: 96%
“…221 The destabilization effect of the added ions was discovered to induce an exceptionally low hydrogen release temperature of ∼323 K from these stabilized NaBH 4 NPs. Using the same method, NaAlH 4 NPs, and LiAlH 4 NPs also enable the release of hydrogen at a much lower temperature of ∼323 K. 222…”
Section: Nanoscale Tuning Strategies For Enhancing the Hydrogen Stora...mentioning
confidence: 99%