Solvation of Beryllium Ions in Water‐Hexamethylphosphoric Triamide Mixtures

Abstract

The relative amounts of the differently solvated species Be(HMPT)i(H2O)2+4‐i have been determined as a function of solvent composition using 31P‐NMR measurements. The formation of a Bc(NO3)+ inner‐sphere complex was established at higher mole fractions of HMPT. The consecutive stability constants of the Be‐HMPT complexes were obtained and compared with those calculated more indirectly using Bjerrum's method [1].