Solvation Structures of Some Transition Metal(II) Ions in a Room-Temperature Ionic Liquid, 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide

Fujii, Kenta; Nonaka, Takahiro; Akimoto, Yu; Umebayashi, Yasuhiro; Ishiguro, Shin‐ichi

doi:10.2116/analsci.24.1377

Cited by 81 publications

(53 citation statements)

References 33 publications

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“…[Emim] + acting as the counterion, in agreement with a configuration interpreted from FT-Raman analysis by Fujii et al [40] and mass spectroscopic analysis by Bortolini et al [41]. Curves are off-set along the y-axis for clarity.…”

Section: Pore Modification Via Alkaline Treatmentsupporting

confidence: 84%

Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads

Arellano

Madani

Huang

et al. 2016

Chemical Engineering Journal

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Carbon dioxide adsorption by zincfunctionalized ionic liquid impregnated into bio-templated mesoporous silica beads, Chemical Engineering Journal (2015), doi: http://dx. AbstractNovel high capacity hybrid sorbents for CO 2 capture have been developed based on zincfunctionalized ionic liquid (IL) impregnated into mesoporous silica beads derived from calcium alginate template beads. Pore modification and development of a surface-confined layer of IL synergistically enhanced the uptake capacity (up to 8.7 wt%) and kinetics of these materials.Spectroscopic and thermophysical signatures of the IL impregnated materials confirm the existence of a highly confined IL layer at low IL:SiO 2 ratio, and multilayer-mimicking bulk phase at higher IL loading. Our results clearly demonstrate that developing a thin layer of zinc-functionalized IL onto porous silica beads effectively enhances the uptake kinetics by exposing interaction sites across a large surface area, and facilitating diffusion through the pore network of the support.

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Section: Pore Modification Via Alkaline Treatmentsupporting

confidence: 84%

Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads

Arellano

Madani

Huang

et al. 2016

Chemical Engineering Journal

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“…The assignments of the absorption bands are summarized in Table 1. The maximum absorption wavelength ( max = 429) and molar absorption coefficient (ε = 18) of 0.1 M Ni(TFSA) 2 in BMPTFSA were close to those in water, suggesting the divalent Ni cations are octahedrally coordinated by six oxygen atoms of TFSA − anions, as reported in Ni(TFSA) 2 /EMITFSA (EMI + : 1-ethyl-3-methylimidazolium) [33]. Thus, the dissolved Ni species is considered as some anionic complexes like [Ni(TFSA) 3 ] − .…”

Section: Solvation Structure Of Ni(ii) In Bmptfsasupporting

confidence: 56%

Electrochemical behavior of Ni(II)/Ni in a hydrophobic amide-type room-temperature ionic liquid

Zhu

Kozuma

Katayama

et al. 2009

Electrochimica Acta

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“…15 BnMA was purchased from Wako, and was purified by distillation under reduced pressure over CaH2 prior to use.…”

Section: Methodsmentioning

confidence: 99%

Specific Solvation of Benzyl Methacrylate in 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide Ionic Liquid

et al. 2013

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Solvation Structures of Some Transition Metal(II) Ions in a Room-Temperature Ionic Liquid, 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide

Cited by 81 publications

References 33 publications

Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads

Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads

Electrochemical behavior of Ni(II)/Ni in a hydrophobic amide-type room-temperature ionic liquid

Specific Solvation of Benzyl Methacrylate in 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide Ionic Liquid

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