2019
DOI: 10.1107/s2052520619007030
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Solvatochromism and mechanochromism observed in a triphenylamine derivative

Abstract: A donor–π–acceptor fluorescent dye, 4‐[N,N‐di(4‐phenyl)amino]benzaldehyde 4‐chlorobenzoyl hydrazone (TPA‐CBH), based on a triphenylamine derivative (TPA) and 4‐chlorobenzoyl hydrazine (CBH) was designed and synthesized. The optical properties of this luminogen were investigated in solutions as well as in the solid states. In the intramolecular charge‐transfer (CT) mechanism, TPA‐CBH exhibits solvatochromism when dissolved in various polar solvents. Aggregation‐induced emission was observed with the changes of … Show more

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