2024
DOI: 10.1002/cphc.202400077
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Solvatochromism in Mixtures of Hydrogen Bond Acceptor (HBA) Solvents with Water

Stefan Spange,
Andreas Seifert

Abstract: The UV/Vis absorption energies νmax of Reichardt's dye B30 with respect to ET(30) and 4‐nitroaniline (NA) are investigated as a function of the solvent composition Nav,z. in co‐solvent/water mixtures. Nav,z. is the average molar concentration of the solvent mixture at a given solvent fraction z. The z can be the mole, the volume or the mass fraction. The co‐solvents considered were acetonitrile, acetone, tetrahydrofuran, pyridine, piperidine and 2‐(diethylamino)‐ethanol. Acetone and acetonitrile can be expecte… Show more

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