Solvent-assisted ligand exchange as a post-synthetic surface modification approach of Zn-based (ZIF-7, ZIF-8) and Co-based (ZIF-9, ZIF-67) zeolitic frameworks for energy storage application

Enhancing the Catalytic Activity of Zeolitic Imidazolate Frameworks (ZIFs) via an Etching and Regrowth Method for CO2 Cycloaddition Reaction

“…3200−3600 cm −1 corresponds to the N−H stretch bond. 18 Additionally, the peaks in the ranges of 600−800 and 900−1350 cm −1 stand for the bending vibration of Hmim, while the peaks at 1250−1500 cm −1 belong to the stretching vibration of Hmim. 14,19 The BET surface areas of all samples were calculated based on the N 2 adsorption and desorption test, as shown in Figure 3c.…”

“…Specifically, the peaks at 421, 2426, and 2927 cm –1 correspond to the stretching vibration of the Zn–N bond, N–H···N bond, and C–H bond in Hmim, respectively, while the broad peak at ca. 3200–3600 cm –1 corresponds to the N–H stretch bond . Additionally, the peaks in the ranges of 600–800 and 900–1350 cm –1 stand for the bending vibration of Hmim, while the peaks at 1250–1500 cm –1 belong to the stretching vibration of Hmim. , The BET surface areas of all samples were calculated based on the N 2 adsorption and desorption test, as shown in Figure c.…”

A Mini Overview of Post Synthetic Modification of Synthesized Zeolitic Imidazolate Frameworks

“…2.1 Solvent-assisted linker exchange SALE is a PSM method used to include novel ligands into ZIFs. SALE enables the substitution of the primary linker compounds in the ZIF with a variety of ligands, allowing the framework characteristics to be adjusted for particular uses [19]. The ZIFs are submerged in a solution with a new linker during the SALE process.…”

High performance of visible-light driven hydrogen production over graphdiyne (g-CnH2n−2)/MOF S-scheme heterojunction

“…It is understood that ZIFs are used as a precursor for preparing porous carbon materials, which can efficiently transfer their morphology and pore structure to carbon materials, and achieve the uniform doping of various atoms. 30–35…”

“…It is understood that ZIFs are used as a precursor for preparing porous carbon materials, which can efficiently transfer their morphology and pore structure to carbon materials, and achieve the uniform doping of various atoms. [30][31][32][33][34][35] Carbon-based materials are widely studied because of their characteristic π-conjugated skeleton. [36][37][38][39][40][41][42] By adjusting the proportion and changing the hybrid category, carbon allotropes with different categories, dimensions and properties can be constructed.…”