Solvent Effect on Electrochemical Properties of a Co(II)‐Based Metallo‐Supramolecular Polymer Film

Hsu, Chih‐Yu; Zhang, Jian; Moriyama, Satoshi; Higuchi, Masayoshi

doi:10.1002/masy.201500136

Cited by 5 publications

(2 citation statements)

References 33 publications

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“…0.97 V, which may be ascribed to the oxidative process from Ni(II) to Ni(III) [ 20 ]. At the reduction region, a characteristic redox-reversible process was detected at −1.16 V from PCo(epy) , which revealed the electrochemical conversion between Co(II) and Co(I) [ 46 , 47 , 48 ]. By comparison, the electrochemical process occurring on the metal centre of PCu(epy) was not found, which implied the redox-inactive property of Cu(II) [ 20 ].…”

Section: Resultsmentioning

confidence: 99%

Synthesis of Bis-Terpyridine-Based Metallopolymers and the Thermoelectric Properties of Their Single Walled Carbon Nanotube Composites

Guo

Wong

2021

Molecules

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Although the organic and the conventional inorganic thermoelectric (TE) materials have been extensively developed in recent years, the number of cases involving conducting metallopolymers is still quite limited. In view of the versatile coordination capability of the terpyridine fraction and the electron-rich nature of the 3,4-ethylenedioxythiophene moiety, a bis-terpyridine-featured ligand was designed, and a series of metallopolymers were then synthesized. Upon the addition of single-walled carbon nanotube (SWCNT), the TE properties of the resulting metallopolymer-SWCNT composite films were investigated. It was found that metal centres played an important role in affecting the morphology of the thin films, which was a key factor that determined the TE performances of the composites. Additionally, the energy levels of the metallopolymers were feasibly tuned by selecting different metal centres. With the combined effects of a uniform and condensed surface and an optimized band structure, the highest power factor was achieved by the Cu(II)-containing metallopolymer-SWCNT composite at the doping ratio of 75%, which reached 38.3 μW·m−1·K−2.

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Section: Resultsmentioning

confidence: 99%

Synthesis of Bis-Terpyridine-Based Metallopolymers and the Thermoelectric Properties of Their Single Walled Carbon Nanotube Composites

Guo

Wong

2021

Molecules

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“…are responsible for changing the direction of monomers in the polymeric backbone. 26,27 Bis-terpyridine ligands are mostly used to construct metallo-supramolecular polymers because of their excellent electronic properties, electrical conductivity, solubility, octahedral self-assembly structures, low spin, strong chelating effect, chemical and thermal stability. 28 The excellent electronic properties of transition-metal ions (e.g.…”

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confidence: 99%

Fe(II)-Based Metallo-Supramolecular Polymer Film for Electrochemical Detection of Nitrite: Studies of Kinetics and Reaction Mechanisms

Awal

Mia

Sarkar

et al. 2023

J. Electrochem. Soc.

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Here, a monometallic supramolecular polymer (SMP) was synthesized for the fabrication of an electrochemical nitrite sensor, and a mechanism for nitrite detection was proposed based on the experimental findings. The SMP (polyFe) was synthesized using a symmetrical ligand containing terpyridine moieties [4′,4′′′′-(1,4- Phenylene) bis(2,2′:6′,2′′-terpyridine)] and ferrous acetate. Various analytical methods, such as ultraviolet/visible titration, field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, and energy dispersive X-ray spectroscopy, were used to characterize polyFe. The molecular weight of polyFe was calculated from the intrinsic viscosity measurement using the Mark-Houwink-Sakurada equation. The electrochemical behavior of the fabricated sensor was investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy. The variation in scan rate from CV was used to investigate the kinetics of nitrite oxidation. A possible reaction mechanism was proposed based on the kinetic studies. The proposed sensor showed a good linear range of 2.49 µM to 1.23 mM and a limit of detection of 0.17 µM. Stability, interference, and reproducibility of the proposed sensor were also investigated. The CV technique was used to demonstrate the applicability of the nitrite sensor for real sample analysis. A satisfactory recovery with a low relative standard deviation was achieved.

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Metallo-Supramolecular Polymers Made of Cobalt and 3,4-Propylenedioxythiophene-Bisterpyridine Complexes for Electrochromic Applications

et al. 2018

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Solvent Effect on Electrochemical Properties of a Co(II)‐Based Metallo‐Supramolecular Polymer Film

Cited by 5 publications

References 33 publications

Synthesis of Bis-Terpyridine-Based Metallopolymers and the Thermoelectric Properties of Their Single Walled Carbon Nanotube Composites

Synthesis of Bis-Terpyridine-Based Metallopolymers and the Thermoelectric Properties of Their Single Walled Carbon Nanotube Composites

Fe(II)-Based Metallo-Supramolecular Polymer Film for Electrochemical Detection of Nitrite: Studies of Kinetics and Reaction Mechanisms

Metallo-Supramolecular Polymers Made of Cobalt and 3,4-Propylenedioxythiophene-Bisterpyridine Complexes for Electrochromic Applications

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