Solvent effect on the structures of three manganese complexes based on azotetrazole-3-hydroxy-2-naphthoic acid: synthesis, structures, and magnetic and fluorescent properties

Abstract

Three MnII complexes, named Mn2(HATNA)2(CH3OH)4 (1), {[Mn3(ATNA)2(DMF)2(H2O)2]·0.5DMF·0.5H2O}n (2, DMF = N,N-dimethylformamide), {Mn6(ATNA)4(H2O)10]·8DMSO·2.5H2O}n (3, DMSO = dimethyl sulphoxide) were successfully synthesized from the reaction of the ligand azotetrazole-3-hydroxy-2-naphthoic acid (H3ATNA) and...