Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy)naphthalene

Anion influence on structure and photoluminescence properties of silver(I) complexes with naphthalene-2,3-diyl-diisonicotinate

“…Naphthalene-2,3-diyl-diisonicotinate (L) was prepared according to the published procedure [32]. Elemental microanalyses (C, H, N) were performed on solid samples at the Pusan Center, KBSI, using a Vario-EL III.…”

“…Recently, we reported anion effects on storage utility in metallacyclodimeric silver(I) complexes with naphthalene-2,3-diyl-dipicolinate containing naphthyl moieties as aromatic walls [31]. But whereas exploitation of naphthalene-based pyridyl ligands employed as aromatic walls has produced intriguing results [32,33], the direct anion dependence on the construction and photoluminescence of silver(I) complexes containing a naphthalene-based spacer remains unexplored. Silver(I) ion has been employed in skeleton-directional units such as linear or T-shaped geometries [34,35].…”

Synthesis and Crystal Structure of Solvated Complexes of Copper(II) with Serine and Phenanthroline and Their Solid-State-to-Solid-State Transformation into One Stable Solvate

“…Complexes with hydrogen bond acceptors and/or donors can form porous structures in which solvent molecules form one-dimensional (1D) chains, two- or three-dimensional (2D or 3D) frameworks. In recent years, porous coordination compounds are materials of interest for their ability of recognition and adsorption of solvent or other guest molecules. − Hence, these type of materials have potential applications in solvent storage or as catalysts . If one of the ligands in such porous materials is chiral (e.g., an amino acid), it may also be used in enantioselective synthesis …”