Solvent free oxidation of ethylbenzene over Ce-BTC MOF

Metal oxide/CeO2 nanocomposites derived from Ce-benzene tricarboxylate (Ce-BTC) adsorbing with metal acetylacetonate complexes for catalytic oxidation of carbon monoxide

“…4(ii), and the corresponding average crystallite size calculated by Scherrer equation was presented in Table 1. For Ce-BTC, the peaks appear at 8.48 , 10.64 , and 18.18 are consistent with the previous reports, 28,29 which suggests that Ce-BTC has been prepared successfully. Regarding the metal oxides, they all exhibit the uorite type cubic CeO 2 phase (28.34 (111), 33.06 (200), 47.36 (220), 56.35 (311), and 59.06 (222)).…”

Synthesis of a Ce-Based MOF-76 with High Yield: A Study of Reaction Parameters Based on a Factorial Design

“…27 FTIR spectra acquired for all synthesized Ce-BTC compounds are presented in Figure S1 (Supplementary Information (SI) section). There was no significant difference between them and they showed bands similar to those performed by Almáši et al 1 and Peng et al, 16 who synthesized MOFs with the cerium metal, being another indicative of success in producing a Ce-based MOF-76. In this sense, the sample Ce-BTC 36 h 130 °C was selected as representative and its IR spectrum is shown in Figure 4, as well H 3 BTC IR spectrum.…”

“…11 MOF-76 represents a family of compounds formed by lanthanide ions and BTC as linker, which was firstly synthesized by Rosi et al 12 and since then it had been synthesized and studied for different applications. [12][13][14][15] Specifically a MOF-76 of cerium, Ce 3+ -based MOF-76, {[Ce(BTC)(H 2 O)]•DMF} n , has been synthesized by Almáši et al, 1 Chevinly et al, 11 Peng et al 16 and Zhang et al 17,18 by solvothermal method, reacting a hydrated cerium salt with BTC ligand in N,N-dimethylformamide (DMF), used as solvent. In their works, the reaction parameters applied in {[Ce(BTC)(H 2 O)]•DMF} n synthesis, such as time and temperature, were not evaluated, but there were variations of these parameters between…”

Visible Light‐Driven BiOBr/Bi2S3@CeMOF Heterostructured Hybrid with Extremely Efficient Photocatalytic Reduction Performance of Nitrophenols: Modeling and Optimization

“…Additionally, for the ternary composite photocatalyst (BiOBr/Bi 2 S 3 @CeMOF) the signal of the diffractog-Figure 1. XRD of BiOBr, Bi 2 S 3 , CeMOF with their standard diffraction peaks and simulated XRD pattern of CeMOF [33] (a) and (b) for BiOBr/ Bi 2 S 3 and BiOBr/ Bi 2 S 3 @CeMOF. rame corresponding to the BiOBr and Bi 2 S 3 in addition to the signals of CeMOF.…”

“…CeMOF exhibit good crystallinity with their distinctive peaks at 2θ 10.1°, 13.2°, and 18.2°, as reported in. [33] The FTIR spectra investigate the compositions and structures of the photocatalysts material, as shown in Figure 2a. The vibrational peaks around 3432 and 1630 cm À 1 are attributed to OH stretching and bending vibrations consecutively for all the prepared matrixes.…”