Solvent-Mediated 1,ω-Bis(isoquinoline)alkane/Iodobismuthate Hybridized Isomers: Structures and Packing Mode Dependent-Photoluminescence/Thermochromisms

Thermal decomposition of DMSO or DMF solvates: an advanced method for obtaining new hybrid bismuth(iii) halides

“…Hybrid halometallates are an intensively studied class of chemical compounds due to their excellent light-absorbing properties, making them promising effective materials for solar cells and photodetectors. 1–4 Some of the most studied hybrid halometallates are halobismuthates with properties such as thermochromism, 5,6 luminescence, 7,8 photochromism, 9,10 and ferroelectricity. 11,12 Potential practical applications of halobismuthates include the solar energy industry 13 and other fields, in particular, the creation of photodetectors 14–16 and light-emitting diodes due to the wide absorption spectrum and low optical band gap values ( E g ) of the compounds.…”

Unusual isostructural Br/I substitution effect on the crystal structure and optical properties of hybrid halobismuthates

“…Hybrid halobismuthates attract the attention of researchers because they are easy to obtain and have low toxicity compared to other representatives of hybrid halometallates. Halobismuthates possess a number of useful physical and chemical properties such as ferroelectricity, [1][2][3][4][5] photochromism, [6][7][8] thermochromism, [9][10][11] luminescence, [12][13][14] and semiconductivity, 15 which makes them convenient model compounds for studying the structure-property relationship in hybrid halometallate compounds.…”