Solvent transfer of graphene oxide for synthesis of tin mono-sulfide graphene composite and application as anode of lithium-ion battery

Tripathi, Alok M.; Mitra, Sagar

doi:10.1016/j.mseb.2016.03.006

Cited by 8 publications

(3 citation statements)

References 77 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[120] Here, 2D MXene Ti 3 C 2 T x NSs provide a reliable substrate for the growth of 0D SnS NPs to efficiently suppress the volume expansion of SnS and prolong the cycle life in Li-ion batteries. Other loaded model based on 0D SnS NPs, such as 0D SnS NP/2D MoS 2 NS/N, P-codoped C heterostructures, [116] 0D SnS NP/ 2D MoS 2 @C heterostructures, [121] 0D SnS NP/N-doped C NS heterostructures, [122] 0D SnS NP/2D reduced graphene oxide (rGO) heterostructures, [123,124] and 0D SnS NP/C nanocomposites, [125] has also widely reported for diverse applications in recent years.…”

Section: Loaded Modelmentioning

confidence: 99%

“…With respect to the electrochemical performances in batteries, although pure SnS nanostructures, such as 0D SnS NPs, [31] 1D SnS nanostructures, [62,66] 2D SnS NSs or nanoplates, [153,184,185] 3D SnS nanoflowers or yolk-shell microstructures, [32,99,186] have made considerable progress in the field of batteries, such as Li or Na-ion batteries and Li-S batteries, yet its low electronic conductivity, large volume expansion and poor cycling stability during charging and discharging, greatly limit its practical applications. To this end, a number of researches has focused on the functionalization of SnS with graphene, [69,101,124,137,158,159] CNTs, [111,112,156,187] C fibers, [28,30,146] conductive polymers, [138] MoS 2 NSs, [116,147,150] etc., to achieve outstanding electrochemical performances. For example, in 2020, 2D SnS nanoplates modified with abundant S vacancies were synthesized by a self-template strategy for Li-ion batteries as advanced anode materials.…”

Section: Batteries and Solar Cellsmentioning

confidence: 99%

See 1 more Smart Citation

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Zhu

et al. 2021

Small Science

View full text Add to dashboard Cite

Tin-based binary chalcogenide Sn-X (X ¼ S, Se, Te) compounds have attracted extensive interest in the optical, optoelectronic, catalysis, and flexible systems due to their intriguing performances. [1][2][3][4][5][6][7] The Sn-X (X ¼ S, Se, Te) compounds are typically layered materials and usually have three crystalline phases: hexagonal, monoclinic, and orthorhombic; orthorhombic phase is denoted by chemical formula SnX, and hexagonal and monoclinic phases are labeled as SnX 2 . [8] Until now, SnSe and SnTe compounds have already achieved great progress in many fields, especially for thermoelectronics and ferroelectrics, [9][10][11][12] and many important reviews have been reported on SnSe and SnTe compounds due to their rapid development. [8,[13][14][15][16] For example, in 2020, Chen et al. [14] summarized a comprehensive overview of controlled synthesis, characterization, and thermoelectric performance in SnSe. In 2018, Shi et al. [8] summarized the growth, characterization, and applications (photovoltaics, supercapacitors, rechargeable batteries, phase-change memory devices, and topological insulator) of SnSe. In 2018, Li et al. [15] reviewed the development of SnS, SnSe, and SnTe, mainly focusing on the controllable tuning of the electron and phonon transport as well as the challenges for further optimization and practical applications. Among Sn-X (X ¼ S, Se, Te) compounds, tin monosulfide (SnS) as a typical black phosphorus analogue, has also received intensive scientific attention due to its unique properties, such as inexpensive, sustainable, suitable bandgap between Si (1.12 eV) and GaAs (1.43 eV), [17] high absorption coefficient (10 À4 cm À1 ), [18] strong mechanical properties, and anisotropic optoelectronic, [19][20][21] which are of great value in optoelectronics, catalysis, sensors, and nanomedicines. [7,[22][23][24][25][26][27] In addition, layered SnS with suitable spacing structures hold promising potentials in the field of lithium (Li)-ion batteries and sodium (Na)-ion batteries due to their relatively high electrical conductivity and theoretical capacity. [28][29][30][31][32] However, although popular SnS has achieved great progress in a variety of fields, few comprehensive reviews have hitherto focused on the field of SnS-based nanostructures and their fascinating applications.Inspired by important reviews on SnSe reported by Chen [14] and Li [8] in recent years, we comprehensively summarized the synthesis, characterization, and the latest progress of SnS-based nanostructures, as shown in Figure 1. First, the most commonly employed techniques (hydrothermal, vapor deposition, electrostatic assembly, etc.) for preparing SnS and SnS-based nanostructures are presented in detail with their recent progress. Furthermore, the fundamental properties (crystal structure, electronic band structure, optical property, and Raman spectroscopy) and diverse applications (batteries, solar cells, catalysis, optoelectronics, sensors, ferroelectrics, thermoelectrics, nonlinear properties, and biomedical applicatio...

show abstract

Section: Loaded Modelmentioning

confidence: 99%

Section: Batteries and Solar Cellsmentioning

confidence: 99%

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Zhu

et al. 2021

Small Science

View full text Add to dashboard Cite

show abstract

“…While graphene can adapt to the large volume change in SnS, the latter can prevent redeposition of graphene. [ 246,247 ] Tao et al [ 248 ] prepared SnS/graphene nanocomposites by in situ reduction of RGO using thiourea. The composite electrode delivered a capacity of 535 mA h g −1 after 50 cycles at 50 mA g −1 .…”

Section: Applicationsmentioning

confidence: 99%

Applications of Tin Sulfide‐Based Materials in Lithium‐Ion Batteries and Sodium‐Ion Batteries

Shan

Pang

2020

Adv Funct Materials

181

View full text Add to dashboard Cite

SnSx (x = 1, 2) compounds are composed of earth‐abundant elements and are nontoxic and low‐cost materials that have received increasing attention as energy materials over the past decades, owing to their huge potential in batteries. Generally, SnSx materials have excellent chemical stability and high theoretical capacity and reversibility due to their unique 2D‐layered structure and semiconductor properties. As a promising matrix material for storing different alkali metal ions through alloying/dealloying reactions, SnSx compounds have broad electrochemical prospects in batteries. Herein, the structural properties of SnSx materials and their advantages as electrode materials are discussed. Furthermore, detailed accounts of various synthesis methods and applications of SnSx materials in lithium‐ion batteries, sodium‐ion batteries, and other new rechargeable batteries are emphasized. Ultimately, the challenges and opportunities for future research on SnSx compounds are discussed based on the available academic knowledge, including recent scientific advances.

show abstract

N‐Doped Carbon‐Coated Mixed‐Phase SnS–SnS₂ Anode with Carbon Nanofibers Skeleton for Improving Dual‐Ion Battery in Concentrated Electrolyte

Fang

Zheng

et al. 2022

Energy Tech

View full text Add to dashboard Cite

Metal sulfides exhibit great potential for anode material due to the lamellar structure. However, the intrinsic low conductivity and large volume expansion result in poor cycle stability. Herein, a porous hierarchical structure (SnS–SnS2)–NC–CF anode material composed of carbon nanofibers skeleton and N‐doped carbon is designed, and a full dual‐ion battery based on the anode is constructed, coupled with natural graphite and high‐concentration electrolyte (6 M LiTFSI + 5% vinylene carbonate). The graphite/(SnS‐SnS2)–NC–CF dual‐ion battery shows a high initial discharge specific capacity up to 154.3 mAh g−1 at a current density of 100 mA g−1 in a working voltage window of 1.0–4.0 V. Also, the battery obtains a considerable capacity of 67.1 mAh g−1 at the high current density of 1000 mA g−1 and achieves an excellent cycling performance up to 2000 cycles with remarkable Coulombic efficiency near 100%. In addition, the battery exhibits a low self‐discharge of 1.83% h−1 and superior fast charge performance. Furthermore, the results of the X‐ray diffraction and scanning electron microscope characterizations further demonstrate good reversibility and stability. Consequently, this work provides a feasible strategy for the design of a high performance dual‐ion battery energy storage device.

show abstract

Solvent transfer of graphene oxide for synthesis of tin mono-sulfide graphene composite and application as anode of lithium-ion battery

Cited by 8 publications

References 77 publications

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Applications of Tin Sulfide‐Based Materials in Lithium‐Ion Batteries and Sodium‐Ion Batteries

N‐Doped Carbon‐Coated Mixed‐Phase SnS–SnS₂ Anode with Carbon Nanofibers Skeleton for Improving Dual‐Ion Battery in Concentrated Electrolyte

Contact Info

Product

Resources

About

Solvent transfer of graphene oxide for synthesis of tin mono-sulfide graphene composite and application as anode of lithium-ion battery

Cited by 8 publications

References 77 publications

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Nanoengineering of Tin Monosulfide (SnS)‐Based Structures for Emerging Applications

Applications of Tin Sulfide‐Based Materials in Lithium‐Ion Batteries and Sodium‐Ion Batteries

N‐Doped Carbon‐Coated Mixed‐Phase SnS–SnS2 Anode with Carbon Nanofibers Skeleton for Improving Dual‐Ion Battery in Concentrated Electrolyte

Contact Info

Product

Resources

About

N‐Doped Carbon‐Coated Mixed‐Phase SnS–SnS₂ Anode with Carbon Nanofibers Skeleton for Improving Dual‐Ion Battery in Concentrated Electrolyte