Solvothermal syntheses and structures of indium(III)-binaphthalenyl dicarboxylate complexes with yellow/blue luminescence

Two novel indium coordination polymers derived from 2,6-pyridinedicarboxylate ligand: Syntheses, structures and photoluminescent properties

“…Cl(1) and Cl (2) atoms occupy the axial vertexes of pentagonal bipyramid with Cl(1)-In(1)-Cl(2) angle being 173.50(3)°, significantly deflected Table 1 Crystal data and structure refinements for 1 and 2. from the ideal value of 180°. All of In-O and In-N distances are similar to those reported for other indium oxygen and indiumnitrogen donor compounds [18,19]. For In(2) ion, it adopts sixcoordination geometry to construct a slightly distorted octahedron by two oxygen atoms, two nitrogen atoms and two chlorine atoms with the bond lengths being 2.1574(14), 2.3515(16) and 2.4289(9) Å for In-O, In-N and In-Cl, respectively ( Fig.…”

“…The emission band for the free 2,6-H 2 pdc ligand is at 375 nm excited at 330 nm and that of the free bipy ligand is at 420 and shoulder bands at 443 and 459 nm excited 340 nm ( Fig. S4), which can be owing to the p * -p transition [17][18][19]. As shown in Fig.…”

“…A 1.5 (C 3 N 2 H 3 )(C 3 N 2 H 4 ) 0.5 ]ÁDMFÁ(CH 3 CN) 0.5 is proved to be a potential candidate for hydrogen storage material [15] and three unique cage-within-cage-based porous materials exhibit high photochemical stability and high CO 2 uptake capacity [16]. In addition, as the d 10 metal ions, In(III)-CPs also display intense photoluminescent emissions [17][18][19]. Therefore, the study on In(III)-CPs may cast some light on the design and synthesis of functional CPs.…”

Synthesis and Structural Studies of Chiral Indium(III) Complexes Supported by Tridentate Diaminophenol Ligands

“…The emergence of indium as an important Lewis acid catalyst and the relative paucity of indium complexes supported by chiral ligands ,− emphasize the importance of developing well-characterized chiral indium complexes. − In this work, we present our investigations into the coordination chemistry and structural characteristics of a family of indium(III) complexes supported by a chiral tridentate diaminophenol ligand, H(NN H O), and provide explanations for the significant halide effect observed in these systems.…”

“…The emergence of indium as an important Lewis acid catalyst and the relative paucity of indium complexes supported by chiral ligands 21,[23][24][25][26][27][28] emphasize the importance of *To whom correspondence should be addressed. E-mail: mehr@ chem.ubc.ca.…”