2023
DOI: 10.1007/s00706-023-03123-x
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Solvothermal synthesis of cobalt PCP pincer complexes from [Co2(CO)8]

Heiko Schratzberger,
Daniel Himmelbauer,
Wolfgang Eder
et al.

Abstract: Treatment of [Co2(CO)8] with the ipso-substituted P(C-X)PY ligands (X = Br, Cl; R = iPr, tBu) bearing Y = NH and CH2 linkers under solvothermal conditions affords the five-coordinate Co(I) and Co(III) complexes [CoI(PCPY-R)(CO)2] and [CoIII(PCPY-R)X2]. The later are paramagnetic exhibiting a solution magnetic moment in the range of 3.0–3.3 μB which is consistent with a d6 intermediate spin system corresponding to two unpaired electrons. In the case of P(C-X)PY ligands (X = Br, Cl; R = tBu; Y = NH) the formatio… Show more

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