Dalton Trans.
 2024
DOI: 10.1039/d4dt00458b
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Soma–Iwamoto-type SCO complex Fe(quinazoline)2[Au(CN)2]2 using the quinazoline-type ligand

Kosuke Kitase,
Daisuke Akahoshi,
Takafumi Kitazawa

Abstract: We have synthesized Fe(quinazoline)2[Au(CN)2]2 (1). Complex 1 shows the Soma–Iwamoto-type bilayer and a spin-crossover (SCO) phenomenon. Mononuclear complex with a hydrogen-bonding network Fe(H2O)2(quinazoline)2[Au(CN)2]2 has also been obtained.

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