A linear radiation model is developed that overcomes the analytical complexity in phase of thermal emission spectroscopy. It is shown that the linear radiation model can result in a simple algebraic relation between the phase of thermal emission and four coating properties, enabling these properties to be determined by nonlinear regression analysis of experimental measurements. Suitability of the linear radiation model to various measurement conditions is explored, and the model is applied to the phase of thermal emission measurements performed on a thermal barrier coating.