1.2. Resumen 5 2. Introduction 9 2.1. An overview 9 2.2. CO2 2.3. CH4 2.4. The importance of accurate CO2 and CH4 mixing ratio measurements 2.5. CIBA station characteristics 2.6. Time series 2.7. Valladolid urban plume analysis 2.8. Motivation of the study 3. Objectives 3.1. General objective 3.2. Specific objectives 4. Material and methods 4.1. Site description 4.2. Monitoring station 4.3. Instrumentation 4.4. Database 4.5. Software employed 4.6. Mathematical equations used 4.7. Statistical techniques 4.8. Graphical summary techniques 4.9. Validation methods 5. List of Original Contributions 6. Original Contributions 6.1. Harmonic function for describing CO2 and CH4 temporal patterns: Original Contribution I 6.2. Kernel functions for describing CO2 and CH4 temporal patterns: Original Contribution II 6.3. Local regression functions for describing CO2 and CH4 temporal patterns: Original Contribution III 101 6.4. Valladolid urban plume influence on the final CO2 and CH4 mixing ratios at CIBA: Original Contribution IV 115 7. General results 133 7.1. CO2 and CH4 temporal analysis 133 7.2. Back-trajectory analysis 136 II 7.3. Validation indicators 8. General discussion 8.1. Temporal pattern evolution 8.2. Mathematical equations for analysing temporal patterns 8.3. Valladolid urban plume analysis 9. Conclusions / Conclusiones 9.1. Conclusions 9.2. Conclusiones 10. References 11. Appendices 11.1. Acronyms 11.2. List of tables and figures 2.1.1.1. The Intergovernmental Panel on Climate Change (IPCC) In 1988 the World Meteorological Organization (WMO) and the United Nations EnvironmentProgram (UNEP) created the Intergovernmental Panel on Climate Change (IPCC) to analyse the problem of global climate change. The IPCC is a group open to all members of the United Nations and WMO (IPCC, 2020a). The function of the IPCC is not to conduct its own research but to analyse, in a comprehensive, objective, open and transparent way, the relevant scientific, technical and socioeconomic information required to understand the scientific elements involved in climate change caused by human activities, its possible repercussions and the possibilities of attenuation and/or adaptation (IPCC, 2020a). In addition, through their evaluations, the IPCC seeks to identify the strength of scientific agreement in different areas and indicates where further research is needed. The IPCC is made up of three different working In 2015, the 21 st Conference of the Parties (COP 21) of the United Nations Framework on Climate Change (UNFCCC) took place in Paris, ending with the adoption of the Paris Agreement by the 195 UNFCCC countries (Boffino et al., 2019). The Paris Agreement establishes the global framework for combating climate change from 2020, promoting a transition towards a low-emission economy in the fight against climate change (Boffino et al., 2019; Pauw et al., 2019). This agreement establishes a plan to reduce emissions of CO2 and other greenhouse gases, aiming to keep global temperature increases to below 2ºC relative to 2.3.1. The CH4 cycle A...