Some kinetic regularities of the polycondensation of glycols with carboxy-containing compounds in the synthesis of polyester resins for tin containers coating

Abstract

C URRENTLY, the biggest share of paints and varnishes intended for painting internal surface of metal canning containers is accounted for by compositions containing epoxy oligomers. Despite the fact that such materials allow to obtain coatings with good adhesion to metal substrates, sufficient chemical resistance and elasticity, they have one significant drawback, which is due to the main component of epoxy resins -bisphenol A.Due to the well-known negative effects of bisphenol A on human health, the use of such materials is currently limited.Promising replacement of these materials are composites based on polyester resins.However, it should be mentioned that the disadvantage of polyester varnishes intended for canning containers is the low resistance of coatings to sterilization when laying food products in containers. The main reason for such low resistance is a relatively high content of ester groups in the structure of these polymers, characterized by low water, alkali and limited acid resistance.To increase the resistance of such coatings, we proposed to introduce fragments of unsaturated monomers (capable of homopolymerization under the conditions of polyester compositions (intended for can-coating) curing) into the composition of their polymer macromolecules. These fragments should create an additional steric hindrance for diffusion to ester groups of destructive molecules of aggressive media and ensure the durability of coatings in general.Synthesis of such polyesters is a typical polycondensation process, and to accelerate it, it is advisable to use various catalytic systems.