Some observations on the determination of phenol using ion selective electrodes

Chan, Wing Hong; Lee, Albert W. M.; Wong, Man Shing

doi:10.1016/0026-265x(89)90093-3

Cited by 4 publications

(3 citation statements)

References 9 publications

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“…Chan et al have developed phenol sensors using PVC membranes [12]. Phenol sensors have also been developed using chitosan and cetyl trimethylammonium phenol (CTAPh) membranes as ionophores [13].…”

Section: Introductionmentioning

confidence: 99%

Development of Potentiometric Phenol Sensors by Nata de Coco Membrane on Screen-Printed Carbon Electrode

Mulyasuryani

Mustaghfiroh

2019

Journal of Analytical Methods in Chemistry

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Nata de coco, a bacterial cellulose as a result of coconut water fermentation, is a conductive polymer with a electrical conductivity of 553 μS/cm and has high mechanical stability. In this study, nata de coco was used as a supporting membrane for the development of phenol sensors in potentiometry. Nata de coco membrane containing phenol is coated on the surface of the printed carbon electrode (screen-printed carbon electrode). The cross-sectional area of the carbon electrode coated with the membrane is 1.5 × 3 mm2, while the reference electrode is Ag/AgCl. The thickness of the electrode membrane affects the Nernstian factor. The optimum Nernstian factor is produced by 100 μm membrane thickness containing 117.5 μg of phenol. Measurement of phenol solution was carried out at pH 11, in the concentration range of 10−8 to 10−2 mol/L, resulting in a Nernstian factor of 41.8 ± 1.3 mV/decade. The Nernstian factor increased to 55.7 ± 0.4 mV/decade if the membrane of the electrode contained 0.1% Fe3O4 nanoparticles. This sensor has been applied in the real sample of river water, resulting in good accuracy and precision.

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Section: Introductionmentioning

confidence: 99%

Development of Potentiometric Phenol Sensors by Nata de Coco Membrane on Screen-Printed Carbon Electrode

Mulyasuryani

Mustaghfiroh

2019

Journal of Analytical Methods in Chemistry

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“…Phenol is an industrial pollutant that is widely used in the production or manufacture of various compounds such as explosives, fertilizers, coal, textiles, pharmaceuticals, and others [1][2][3]. Phenol can affect the taste and smell of drinking water with concentrations limit mg/ L. The surface of carbon paste electrode is easily modified so widely used in the electrochemical field because of its low cost, wide potential range, low background current, and minimum sample used in the measurement.…”

Section: Introductionmentioning

confidence: 99%

Fabrication of Carbon Paste Electrode Modified with Phenol Imprinted Polyaniline as a Sensor for Phenol Analysis by Potentiometric

Rahmadhani

Setiyanto

Zulfikar

2018

MSF

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A phenol imprinted polymer modified electrode has been prepared by electropolymerization technique in the solution containing aniline as monomer and phenol as a template onto carbon paste electrode surface. A potentiometric method was used to evaluate the performance of the electrodes. Optimization of aniline and phenol composition and a number of polymerization cycles was investigated based on the Nernstian factor. The performance of the electrode sensor is affected by the pH of the analyte solution. Based on the potential response of three different electrodes, it is known that MIP modified electrode has better sensitivity than non-imprinted electrode or bare carbon paste electrode.

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“…Elektroda selektif ion (ESI) yang pernah dikembangkan oleh Chan, et al (1989) mendeteksi fenol secara tidak langsung dengan cara menderivatisasi fenol menjadi fenoksiasetat menggunakan asam kloroasetat yang kemudian diembankan pada membran PVC. ESI ini memiliki karakter bilangan Nernst 68,9 mV/dekade, kisaran konsentrasi 3,2x10-4 hingga 10-1 M, pH larutan 7,5 hingga 11, dan waktu respon 1 menit.…”

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Penentuan Kadar Fenol Dalam Air Menggunakan Sensor Fenol

Tyas

Aini

Wari

2015

JPS

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Tujuan penelitian adalah untuk mengetahui kondisi optimum serta penggunaan sensor fenol dalam menentukan kadar fenol dalam air. Metode penelitian dilakukan dengan membuat sensor fenol menggunakan Screen Printed Carbon Electrode (SPCE) yang dilapisi dengan membran kitosan yang telah diembankan ionofor CTAPh (Cethyltrimethylammonium phenoxide). Kinerja sensor fenol diamati pada berbagai variasi konsentrasi ionofor, ketebalan membran dan pH larutan. Konsentrasi ionofor yang dipelajari adalah 0,5%; 1%;1,5%; 2%; dan 2,5%. Ketebalan membran diatur pada ketebalan 60µ m, 80µ m, 100µ m,110µ m. Larutan fenol dikondisikan pada pH 9, 10, 11, 12. Hasil penelitian menunjukkan kinerja sensor fenol optimum pada konsentrasi 1,5%, ketebalan membran 60µ m, dan pH larutan 11. Sensor fenol yang dihasilkan pada penelitian ini memiliki bilangan Nernst sebesar 54,437mV/dekade, kisaran konsentrasi 10-8-10-5M (0,001-1ppm), kosentrasi terkecil yang digunakan 0,001 ppm dan waktu respon 60 detik. Sensor fenol dapat digunakan untuk menentukan kadar fenol dalam sampel air dengan kadar dibawah batas deteksi metode standar.Kata kunci: elektroda selektif ion, ionofor, Screen Printed Carbon Electrode (SPCE), sensor fenol

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Some observations on the determination of phenol using ion selective electrodes

Cited by 4 publications

References 9 publications

Development of Potentiometric Phenol Sensors by Nata de Coco Membrane on Screen-Printed Carbon Electrode

Development of Potentiometric Phenol Sensors by Nata de Coco Membrane on Screen-Printed Carbon Electrode

Fabrication of Carbon Paste Electrode Modified with Phenol Imprinted Polyaniline as a Sensor for Phenol Analysis by Potentiometric

Penentuan Kadar Fenol Dalam Air Menggunakan Sensor Fenol

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